Supramolecular Associates of Nickel(II) Complexes with Nitro-Substituted Tetradentate Schiff Bases

Supramolecular Associates of Nickel(II) Complexes with Nitro-Substituted Tetradentate Schiff Bases

Crystal structures of N , N '-ethylenebis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SalEn)] and N , N '-(2,3-dimethylbutane-2,3-diyl)bis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SaltmEn)] were determined by single crystal X-ray diffraction analysis. The [Ni(3-NO 2 SalEn)] co...

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Veröffentlicht in:Russian journal of general chemistry 2020-03, Vol.90 (3), p.444-447
Hauptverfasser: Karushev, M. P., Khoroshilova, O. V., Kurchavov, D. S., Novozhilova, M. V., Chepurnaya, I. A., Timonov, A. M.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Crystal structure
Crystals
Imines
Nickel
Schiff bases
Single crystals
Structure
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Zusammenfassung:Crystal structures of N , N '-ethylenebis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SalEn)] and N , N '-(2,3-dimethylbutane-2,3-diyl)bis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SaltmEn)] were determined by single crystal X-ray diffraction analysis. The [Ni(3-NO 2 SalEn)] complex forms supramolecular associates in the crystal phase, which affects its solubility, thermogravimetric, and spectral characteristics.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363220030172