Polymer-Immobilized Clusters and Metal Nanoparticles in Catalysis

Recent advances in the synthesis of polymer-immobilized clusters and metal nanoparticles and their use in catalysis of many organic reactions were presented. The main types of polymer-immobilized catalysts were considered, including cluster-containing polymers, polymer-protected metal nanoparticles...

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Veröffentlicht in:Kinetics and catalysis 2020-03, Vol.61 (2), p.198-223
Hauptverfasser: Dzhardimalieva, G. I., Zharmagambetova, A. K., Kudaibergenov, S. E., Uflyand, I. E.
Format: Artikel
Sprache:eng
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Zusammenfassung:Recent advances in the synthesis of polymer-immobilized clusters and metal nanoparticles and their use in catalysis of many organic reactions were presented. The main types of polymer-immobilized catalysts were considered, including cluster-containing polymers, polymer-protected metal nanoparticles fixed on inorganic supports, and gel-immobilized catalysts. Special attention was paid to the role of the polymer matrix. It functions not only as a stabilizing agent that prevents the aggregation of nanoparticles and their leaching into the reaction medium, but also as a ligand in the coordination sphere of the metal site, which allows the advantages of homogeneous and heterogeneous catalysts to be combined in one catalyst.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158420020044