A combined experimental and theoretical study of the magnetic properties of bulk CoFe2O4

This work is devoted to studying experimentally and theoretically the structural and magnetic properties of bulk cobalt spinel ferrite. Solid-state reaction with optimized synthesis conditions is used to prepare CoFe 2 O 4 . The crystallization of CoFe 2 O 4 in the FCC structure was confirmed with t...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2020-05, Vol.126 (5), Article 325
Hauptverfasser: Lamouri, R., Fkhar, L., Salmani, E., Mounkachi, O., Hamedoun, M., Ait Ali, M., Benyoussef, A., Ez-Zahraouy, H.
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Sprache:eng
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Zusammenfassung:This work is devoted to studying experimentally and theoretically the structural and magnetic properties of bulk cobalt spinel ferrite. Solid-state reaction with optimized synthesis conditions is used to prepare CoFe 2 O 4 . The crystallization of CoFe 2 O 4 in the FCC structure was confirmed with the X-ray diffraction. The microstructural properties are performed using the scanning electron microscopy. The magnetic properties of the bulk cobalt ferrite were performed experimentally using the superconducting quantum interference device magnetometer (SQUID). Monte Carlo simulation with periodic boundary conditions was used to simulate bulk CoFe 2 O 4 with a large enough size of the system. The obtained magnetization and susceptibility as a function of temperature show that CoFe 2 O 4 exhibits a second-order transition to paramagnetic phase around 725 K. To carry out the maximum energy product, experimental and theoretical magnetic hysteresis loops at room temperature were performed. It is found that the synthesized CoFe 2 O 4 has a high saturation magnetization of about 87.89 emu/g, which is close to the theoretical value of 97.13 emu/g. Lower coercivity–sugariness ratio was found which indicates that bulk cobalt spinel ferrite is a magnetic multi-domain in nature. To evaluate the efficiency of bulk CoFe 2 O 4 , the maximum energy product was calculated at room temperature. Our results demonstrate from a microscopic to the macroscopic scale the performance of CoFe 2 O 4 as a promising magnetic material in the new energy technology generation.
ISSN:0947-8396
1432-0630
DOI:10.1007/s00339-020-03510-9