Catalytic cycloalumination of 1,2-dienes in the total synthesis of natural grenadamide and lyngbyoic acid
An original method for the total synthesis of natural grenadamide and its precursor lyngbyoic acid with high stereoselectivity and yields was developed using the catalytic cycloalumination reaction of 1,2-dienes with Et 3 Al in the presence of 5 mol.% of Cp 2 ZrCl 2 (Dzhemilev reaction) as a key ste...
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| Veröffentlicht in: | Russian chemical bulletin 2020-02, Vol.69 (2), p.386-389 |
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| container_title | Russian chemical bulletin |
| container_volume | 69 |
| creator | D´yakonov, V. A. Makarov, A. A. Andreev, E. N. Makarova, E. Kh Dzhemileva, L. U. Khalilov, L. M. Dzhemilev, U. M. |
| description | An original method for the total synthesis of natural grenadamide and its precursor lyngbyoic acid with high stereoselectivity and yields was developed using the catalytic cycloalumination reaction of 1,2-dienes with Et
3
Al in the presence of 5 mol.% of Cp
2
ZrCl
2
(Dzhemilev reaction) as a key step. |
| doi_str_mv | 10.1007/s11172-020-2772-0 |
| format | Article |
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2
ZrCl
2
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3
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2
ZrCl
2
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| ispartof | Russian chemical bulletin, 2020-02, Vol.69 (2), p.386-389 |
| issn | 1066-5285 1573-9171 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Brief Communication Chemistry Chemistry and Materials Science Chemistry/Food Science Dienes Inorganic Chemistry Organic Chemistry Stereoselectivity |
| title | Catalytic cycloalumination of 1,2-dienes in the total synthesis of natural grenadamide and lyngbyoic acid |
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