High temperature Fe(iii) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes

High temperature Fe(iii) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H3ATD) was used to synthesize three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal FeIII ions.

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Veröffentlicht in:Inorganic chemistry frontiers 2020-01, Vol.7 (7), p.1526-1531
Hauptverfasser: Zhi-Jian Ouyang, Xiao-Ying, Mo, Yang, Meng, Li, Zhong, Chen, Wen-Bin, Gao, Song, Dong, Wen
Format: Artikel
Sprache:eng
Schlagworte:
Crossovers
Crystallography
High temperature
Inorganic chemistry
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Zusammenfassung:An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H3ATD) was used to synthesize three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal FeIII ions.
ISSN:2052-1545
2052-1553
DOI:10.1039/c9qi01560d