Mechanisms of the Catalytic Hydrochlorination of Acetylene: Active Sites, Isotope Effects, and Stereoselectivity

Mechanisms of the Catalytic Hydrochlorination of Acetylene: Active Sites, Isotope Effects, and Stereoselectivity

The mechanisms of acetylene vapour-phase hydrochlorination over chloro complexes of noble metals were reviewed. The nature of the active sites of heterogeneous catalysts, isotope effects of HCl/DCl, stereochemistry of reaction products, possible stepwise mechanisms, and mechanisms of individual step...

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Veröffentlicht in:Kinetics and catalysis 2020, Vol.61 (1), p.58-79
Hauptverfasser: Krasnyakova, T. V., Nikitenko, D. V., Mitchenko, S. A.
Format: Artikel
Sprache:eng
Schlagworte:
Acetylene
Catalysis
Chemistry
Chemistry and Materials Science
Coordination compounds
Hydrochlorination
Isotopes
Noble metals
Physical Chemistry
Reaction products
Stereochemistry
Stereoselectivity
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Zusammenfassung:The mechanisms of acetylene vapour-phase hydrochlorination over chloro complexes of noble metals were reviewed. The nature of the active sites of heterogeneous catalysts, isotope effects of HCl/DCl, stereochemistry of reaction products, possible stepwise mechanisms, and mechanisms of individual steps were considered.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158420010036