Exfoliated MoS2@C nanosheets as anode for sodium/potassium storage

Due to high theoretical capacity (670 mA h g −1 ), MoS 2 can become a good application for energy storage. It is reported that the layer spacing of MoS 2 can be exfoliated, which improves Na + /K + insertion/extraction and promotes electron diffusion and ion transport. So, we obtained exfoliated MoS...

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Veröffentlicht in:Ionics 2020-04, Vol.26 (4), p.1779-1786
Hauptverfasser: Chen, Zhi, Chen, Suilong, Zhang, Hanfu, Liu, Mingqiang, Feng, Zhjun, Li, Xibao, Huang, Juntong, Guo, Di
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Sprache:eng
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Zusammenfassung:Due to high theoretical capacity (670 mA h g −1 ), MoS 2 can become a good application for energy storage. It is reported that the layer spacing of MoS 2 can be exfoliated, which improves Na + /K + insertion/extraction and promotes electron diffusion and ion transport. So, we obtained exfoliated MoS 2 nanosheets with the modification of a carbon layer, in order to form exfoliated MoS 2 @C nanosheets. With the analysis of XRD and TEM, it was found that the larger interlayer spacing was obtained. As the anodes for sodium ion batteries (SIBs), the exfoliated MoS 2 nanosheet electrode showed a high capacity (641 mA h g −1 at 50 mA g −1 ) and maintained a capacity of 214 mA h g −1 at 1000 mA g −1 after 400 cycles. Moreover, it was discussed as anode for potassium ion batteries (KIBs). It can be found that the electrode had 241 mA h g −1 at 100 mA g −1 after 20 cycles.
ISSN:0947-7047
1862-0760
DOI:10.1007/s11581-019-03351-4