In Situ Surface Modification for Improving the Electrochemical Performance of Ni‐Rich Cathode Materials by Using ZrP2O7

Ni‐rich layered LiNi0.8Mn0.1Co0.1O2 (NCM811) cathode material has promising prospects for high capacity batteries at acceptable cost. However, LiNi0.8Mn0.1Co0.1O2 cathode material suffers from surface structure instability and capacity degradation upon cycling. In this study, in situ ZrP2O7 coating...

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Veröffentlicht in:ChemSusChem 2020-03, Vol.13 (6), p.1603-1612
Hauptverfasser: Hu, Guorong, Zhang, Zhiyong, Li, Tianfan, Gan, Zhanggen, Du, Ke, Peng, Zhongdong, Xia, Jin, Tao, Yong, Cao, Yanbing
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Sprache:eng
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Zusammenfassung:Ni‐rich layered LiNi0.8Mn0.1Co0.1O2 (NCM811) cathode material has promising prospects for high capacity batteries at acceptable cost. However, LiNi0.8Mn0.1Co0.1O2 cathode material suffers from surface structure instability and capacity degradation upon cycling. In this study, in situ ZrP2O7 coating is introduced to provide a protective structure. The optimum modification amount is 1.0 wt %. A series of characterization methods (X‐ray diffraction, high‐resolution transmission electron microscopy, and X‐ray photoelectron spectroscopy) verify the generation and structure of the coating layer. Electrochemical performance tests demonstrate that the cycle retention rate increases from 66.35 to 86.92 % after 100 cycles at 1 C rate. The dense inorganic pyrophosphate layer not only has chemical stability against the electrolyte but also eliminates surface residual lithium. The protective layer and the matrix are strongly joined by high‐temperature heating, thereby giving a certain mechanical strength and protecting the overall structure of the topography. Therefore, the cycle and rate performance are enhanced by the modification with ZrP2O7. Cathodes with coats: In situ ZrP2O7 coating is introduced to provide a protective structure around Ni‐rich layered LiNi0.8Mn0.1Co0.1O2 (NCM811) cathode material, which has a high capacity for use in batteries at acceptable cost but suffers from surface structure instability and capacity degradation upon cycling. With the optimum coating amount of 1.0 wt %, the cycle retention rate increases from 66.35 % to 86.92 % after 100 cycles at 1 C.
ISSN:1864-5631
1864-564X
DOI:10.1002/cssc.201902219