Pushing the limits of single chain compaction analysis by observing specific size reductions via high resolution mass spectrometry
Herein, we push the limits of single chain nanoparticle (SCNP) analysis to directly observe the specific compaction of defined single chains dependent on the number of compaction steps utilizing a copolymer consisting of styrene and chloromethylstyrene, compacted via Friedel–Crafts alkylation. Our s...
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Veröffentlicht in: | Polymer chemistry 2020-03, Vol.11 (10), p.1696-1701 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Herein, we push the limits of single chain nanoparticle (SCNP) analysis to directly observe the specific compaction of defined single chains dependent on the number of compaction steps utilizing a copolymer consisting of styrene and chloromethylstyrene, compacted
via
Friedel–Crafts alkylation. Our study critically expands the boundaries of SCNP characterization
via
size exclusion chromatography coupled with high resolution electrospray ionization mass spectrometry (SEC-ESI-MS), highlighting the unique compositional and structural information that can be derived
via
this technique. |
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ISSN: | 1759-9954 1759-9962 |
DOI: | 10.1039/C9PY01910C |