Chirality transcription in the anion-coordination-driven assembly of tetrahedral cages

Chirality transcription in the anion-coordination-driven assembly of tetrahedral cages

Enantiopure A 4 L 4 tetrahedral cages (either ΔΔΔΔ or ΛΛΛΛ) were obtained through the anion-coordination-driven assembly (ACDA) of phosphate anions with C 3 -symmetric tris-bis(urea) ligands bearing chiral groups. Enantiopure A 4 L 4 tetrahedral cages were obtained through chirality transfer in the...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-02, Vol.56 (16), p.2475-2478
Hauptverfasser: Fu, Jin, Zheng, Bo, Zhang, Huizheng, Zhao, Yanxia, Zhang, Dan, Zhang, Wenyao, Yang, Xiao-Juan, Wu, Biao
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Assembly
Cages
Chirality
Coordination
Crystallography
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Zusammenfassung:Enantiopure A 4 L 4 tetrahedral cages (either ΔΔΔΔ or ΛΛΛΛ) were obtained through the anion-coordination-driven assembly (ACDA) of phosphate anions with C 3 -symmetric tris-bis(urea) ligands bearing chiral groups. Enantiopure A 4 L 4 tetrahedral cages were obtained through chirality transfer in the anion-coordination-driven assembly (ACDA) of chiral C 3 -symmetric tris-bis(urea) ligands with phosphate.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc09752j