Immobilization of AgCl@TiO2 on the woven wire mesh: Sunlight-responsive environmental photocatalyst with high durability

•Improvement of photocatalytic activity of AgCl incorporation in TiO2.•Immobilization of photocatalyst on woven stainless steel wire mesh for degradation of methamphetamine.•Best photodegradation efficiency was achieved in film thickness of 1629 nm.•Enhancement of photocurrent density of AgCl@TiO2 i...

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Veröffentlicht in:Solar energy 2020-01, Vol.196, p.653-662
Hauptverfasser: Azizi-Toupkanloo, Hossein, Karimi-Nazarabad, Mahdi, Amini, Gholam-Reza, Darroudi, Abolfazl
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creator Azizi-Toupkanloo, Hossein
Karimi-Nazarabad, Mahdi
Amini, Gholam-Reza
Darroudi, Abolfazl
description •Improvement of photocatalytic activity of AgCl incorporation in TiO2.•Immobilization of photocatalyst on woven stainless steel wire mesh for degradation of methamphetamine.•Best photodegradation efficiency was achieved in film thickness of 1629 nm.•Enhancement of photocurrent density of AgCl@TiO2 is 2.1 time greater than TiO2. The immobilized AgCl@TiO2 photocatalytic thin films were fabricated via electrophoretic deposition method. Affordability, scalability, and high chemical stability are some valuable characteristics making woven stainless steel wire mesh a suitable substrate for fabrication of photocatalyst film. The photocatalytic degradation efficiency of the thin film was investigated by removing hard-degradable methamphetamine under natural solar light. The AgCl@TiO2 photocatalyst with AgCl content of about 5% showed the most photocatalytic degradation efficiency. Using Mott-Schottky plots, the flat band potential of prepared photocatalysts was estimated. The flat band potential showed that the conduction band of AgCl@TiO2 is a better candidate for production of superoxide radicals than TiO2. A film thickness of 1629 nm yields optimal photodegradation efficiency. A series of ten sequential cycles for photodegradation of methamphetamine was conducted using thin film which caused neither significant destruction on photocatalytic substrate nor any considerable reduction in efficiency whatsoever. The AgCl@TiO2 thin film-induced mineralization of methamphetamine was reported to be approximately around 91 percent. The photoelectrochemical performance of TiO2 and AgCl@TiO2 thin film was evaluated by LSV technique under solar light and results show thatafter incorporation of AgCl, the photocurrent density corresponding to the oxygen evolution reaction significantly increased to 1.8 mA cm−2 at 1.23 V vs RHE.
doi_str_mv 10.1016/j.solener.2019.12.046
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The immobilized AgCl@TiO2 photocatalytic thin films were fabricated via electrophoretic deposition method. Affordability, scalability, and high chemical stability are some valuable characteristics making woven stainless steel wire mesh a suitable substrate for fabrication of photocatalyst film. The photocatalytic degradation efficiency of the thin film was investigated by removing hard-degradable methamphetamine under natural solar light. The AgCl@TiO2 photocatalyst with AgCl content of about 5% showed the most photocatalytic degradation efficiency. Using Mott-Schottky plots, the flat band potential of prepared photocatalysts was estimated. The flat band potential showed that the conduction band of AgCl@TiO2 is a better candidate for production of superoxide radicals than TiO2. A film thickness of 1629 nm yields optimal photodegradation efficiency. A series of ten sequential cycles for photodegradation of methamphetamine was conducted using thin film which caused neither significant destruction on photocatalytic substrate nor any considerable reduction in efficiency whatsoever. The AgCl@TiO2 thin film-induced mineralization of methamphetamine was reported to be approximately around 91 percent. The photoelectrochemical performance of TiO2 and AgCl@TiO2 thin film was evaluated by LSV technique under solar light and results show thatafter incorporation of AgCl, the photocurrent density corresponding to the oxygen evolution reaction significantly increased to 1.8 mA cm−2 at 1.23 V vs RHE.</description><identifier>ISSN: 0038-092X</identifier><identifier>EISSN: 1471-1257</identifier><identifier>DOI: 10.1016/j.solener.2019.12.046</identifier><language>eng</language><publisher>New York: Elsevier Ltd</publisher><subject>AgCl@TiO2 thin film ; Conduction ; Conduction bands ; Durability ; Efficiency ; Electrophoretic deposition ; Fabrication ; Film thickness ; Immobilization ; Methamphetamine ; Mineralization ; Organic chemistry ; Oxygen evolution reactions ; Photocatalysis ; Photocatalysts ; Photocatalytic degradation ; Photodegradation ; Photoelectric effect ; Photoelectric emission ; Photoelectrochemical ; Silver chloride ; Solar energy ; Stainless steel ; Stainless steels ; Substrates ; Superoxide ; Thin films ; Titanium dioxide ; Wire cloth ; Woven wire mesh</subject><ispartof>Solar energy, 2020-01, Vol.196, p.653-662</ispartof><rights>2020 International Solar Energy Society</rights><rights>Copyright Pergamon Press Inc. 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The photoelectrochemical performance of TiO2 and AgCl@TiO2 thin film was evaluated by LSV technique under solar light and results show thatafter incorporation of AgCl, the photocurrent density corresponding to the oxygen evolution reaction significantly increased to 1.8 mA cm−2 at 1.23 V vs RHE.</description><subject>AgCl@TiO2 thin film</subject><subject>Conduction</subject><subject>Conduction bands</subject><subject>Durability</subject><subject>Efficiency</subject><subject>Electrophoretic deposition</subject><subject>Fabrication</subject><subject>Film thickness</subject><subject>Immobilization</subject><subject>Methamphetamine</subject><subject>Mineralization</subject><subject>Organic chemistry</subject><subject>Oxygen evolution reactions</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photocatalytic degradation</subject><subject>Photodegradation</subject><subject>Photoelectric effect</subject><subject>Photoelectric emission</subject><subject>Photoelectrochemical</subject><subject>Silver chloride</subject><subject>Solar energy</subject><subject>Stainless steel</subject><subject>Stainless steels</subject><subject>Substrates</subject><subject>Superoxide</subject><subject>Thin films</subject><subject>Titanium dioxide</subject><subject>Wire cloth</subject><subject>Woven wire mesh</subject><issn>0038-092X</issn><issn>1471-1257</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkEFv2zAMhYVhA5pl-wkFBPRsV5Ity9qlK4J2CxAgh_awm6DIdK3AljJJcZb9-ilI7zuRBN_jAz-EbikpKaHN_b6MfgQHoWSEypKyktTNB7SgtaAFZVx8RAtCqrYgkv26QZ9j3BNCBW3FAv1ZT5Pf2dH-1cl6h32PH99W4_dXu2U4z2kAfPIzOHyyAfAEcfiGX45utG9DKgLEg3fRzoDBzTZ4N4FLesSHwSdvdG7PMWVrGvCQHbg7Bn1JS-cv6FOvxwhf3-sSvTw_va5-Fpvtj_XqcVOYqhKp4EB4LVvKGy2EaXXNtSas1r0xtKnr3a4xUndGdpLxvpHQi1bKrmtqqChn1RLdXa8egv99hJjU3h-Dy4GKVTzzEKThWcWvKhN8jAF6dQh20uGsKFEXxGqv3hGrC2JFmcqIs-_h6oP8wGzzNhoLzkCXWZmkOm__c-EfO9KKVw</recordid><startdate>20200115</startdate><enddate>20200115</enddate><creator>Azizi-Toupkanloo, Hossein</creator><creator>Karimi-Nazarabad, Mahdi</creator><creator>Amini, Gholam-Reza</creator><creator>Darroudi, Abolfazl</creator><general>Elsevier Ltd</general><general>Pergamon Press Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7ST</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0001-7342-3897</orcidid></search><sort><creationdate>20200115</creationdate><title>Immobilization of AgCl@TiO2 on the woven wire mesh: Sunlight-responsive environmental photocatalyst with high durability</title><author>Azizi-Toupkanloo, Hossein ; 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The immobilized AgCl@TiO2 photocatalytic thin films were fabricated via electrophoretic deposition method. Affordability, scalability, and high chemical stability are some valuable characteristics making woven stainless steel wire mesh a suitable substrate for fabrication of photocatalyst film. The photocatalytic degradation efficiency of the thin film was investigated by removing hard-degradable methamphetamine under natural solar light. The AgCl@TiO2 photocatalyst with AgCl content of about 5% showed the most photocatalytic degradation efficiency. Using Mott-Schottky plots, the flat band potential of prepared photocatalysts was estimated. The flat band potential showed that the conduction band of AgCl@TiO2 is a better candidate for production of superoxide radicals than TiO2. A film thickness of 1629 nm yields optimal photodegradation efficiency. 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subjects AgCl@TiO2 thin film
Conduction
Conduction bands
Durability
Efficiency
Electrophoretic deposition
Fabrication
Film thickness
Immobilization
Methamphetamine
Mineralization
Organic chemistry
Oxygen evolution reactions
Photocatalysis
Photocatalysts
Photocatalytic degradation
Photodegradation
Photoelectric effect
Photoelectric emission
Photoelectrochemical
Silver chloride
Solar energy
Stainless steel
Stainless steels
Substrates
Superoxide
Thin films
Titanium dioxide
Wire cloth
Woven wire mesh
title Immobilization of AgCl@TiO2 on the woven wire mesh: Sunlight-responsive environmental photocatalyst with high durability
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