Formation of solid solutions in wide miscibility-gap perovskite-type oxide system of Ba1−xCaxZrO3 over the entire Ca composition range
Formation of solid solutions was examined in a wide miscibility gap system of Ba1−xCaxZrO3 by preparing film samples having amorphous structures with the help of rf magnetron sputtering and then annealing the amorphous film samples at a moderate temperature condition. Ba1−xCaxZrO3 solid solutions we...
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Veröffentlicht in: | Journal of the Ceramic Society of Japan 2020/02/01, Vol.128(2), pp.80-83 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Formation of solid solutions was examined in a wide miscibility gap system of Ba1−xCaxZrO3 by preparing film samples having amorphous structures with the help of rf magnetron sputtering and then annealing the amorphous film samples at a moderate temperature condition. Ba1−xCaxZrO3 solid solutions were successfully formed as monophasic products over the entire Ca composition range, indicating the usefulness of the method for the formation of solid solutions in perovskite-type oxides, and Ca composition dependence of the permittivity was revealed in the solid-solution system. |
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ISSN: | 1882-0743 1348-6535 |
DOI: | 10.2109/jcersj2.19197 |