High ionic conductivities of composites of Li4(BH4)3I with two-dimensional MoS2 at room temperature

Li4(BH4)3I–MoS2 composites with high Li-ion conductivity were synthesized by simple ball milling. Owing to the synergic effect of halide substitutions and the formation of the highly disordered interface between the two phases, the composite delivers an ionic conductivity as high as 2.78 × 10−4 S cm−1 at room temperature, which is over three orders of magnitude higher than that of pristine LiBH4 and nearly three times higher than our previously studied LiBH4–MoS2 (1 × 10−4 S cm−1). The ionic conductivity of Li4(BH4)3I–MoS2 at room temperature is also superior over Li4(BH4)3I solid solutions. Additionally, Li4(BH4)3I–MoS2 exhibits a wide electrochemical stability window of −1 to 5 V and demonstrates an excellent electrochemical stability against Li foil. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) measurements on Li4(BH4)3I–MoS2 demonstrate that parent phases of these composites were well preserved after ball milling. Field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) reveal a highly dispersed interface between two phases, which acts as a favorable pathway for Li+ conduction. This work proposes a new strategy for solid electrolytes, offering a possibility for those two-dimensional materials to be scaffolds for superior solid electrolytes. •The Li4(BH4)3I–MoS2 composite delivers an ionic conductivity of 2.78 × 10−4 S cm−1 at room temperature.•The enhancement can be attributed to synergic effect of halide substitution and formation of the highly disordered interface.•Li4(BH4)3I–MoS2 exhibits a wide electrochemical stability window of −1 to 5 V.