Highly Selective Electrochemical Reduction of CO2 to Alcohols on an FeP Nanoarray

Electrochemical reduction of CO2 into various chemicals and fuels provides an attractive pathway for environmental and energy sustainability. It is now shown that a FeP nanoarray on Ti mesh (FeP NA/TM) acts as an efficient 3D catalyst electrode for the CO2 reduction reaction to convert CO2 into alcohols with high selectivity. In 0.5 m KHCO3, such FeP NA/TM is capable of achieving a high Faradaic efficiency (FECH3OH ) up to 80.2 %, with a total FECH3OH+C2H5OH of 94.3 % at −0.20 V vs. reversible hydrogen electrode. Density functional theory calculations reveal that the FeP(211) surface significantly promotes the adsorption and reduction of CO2 toward CH3OH owing to the synergistic effect of two adjacent Fe atoms, and the potential‐determining step is the hydrogenation process of *CO. A FeP nanoarray on Ti mesh (FeP NA/TM) performs efficiently to electrocatalyze CO2 reduction to alcohols with a high Faradaic efficiency (FE) up to 80.2 % and a total FE of 94.3 % at −0.20 V vs. RHE. Calculations reveal that the FeP(211) surface significantly promotes the adsorption and reduction of CO2 toward CH3OH by the synergistic effect of two adjacent Fe atoms; the potential‐determining step is the hydrogenation process of *CO.