Silica-supported Alkylammonium Formate Catalyst for Hydrosilylation of Carbon Dioxide

An amorphous silica-supported alkylammonium formate catalyst for the reductive transformation of carbon dioxide using silane as a reductant was developed. Alkylammonium iodide was grafted on amorphous silica, followed by anion exchange of iodide to formate. The successful synthesis of the catalyst w...

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Veröffentlicht in:	Chemistry letters 2019-11, Vol.48 (11), p.1417-1420
Hauptverfasser:	Pramudita, Ria Ayu, Nakagawa, Chihiro, Manaka, Yuichi, Motokura, Ken
Format:	Artikel
Sprache:	eng
Schlagworte:	Anion exchanging Carbon dioxide Catalysts Catalytic activity Chemical analysis Chemical synthesis Hydrosilylation Infrared analysis Infrared spectroscopy NMR spectroscopy Silicon dioxide Spectrum analysis
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creator	Pramudita, Ria Ayu Nakagawa, Chihiro Manaka, Yuichi Motokura, Ken
description	An amorphous silica-supported alkylammonium formate catalyst for the reductive transformation of carbon dioxide using silane as a reductant was developed. Alkylammonium iodide was grafted on amorphous silica, followed by anion exchange of iodide to formate. The successful synthesis of the catalyst was confirmed by solid-state 13C CP/MAS NMR spectroscopy, FT-IR spectroscopy, and elemental analysis. While silica-supported alkylammonium formate exhibited catalytic activity in the hydrosilylation of CO2 to generate silylformate as the main product, no catalytic activity was observed in the presence of silica-supported alkylammonium iodide.
doi_str_mv	10.1246/cl.190649
format	Article
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Anion exchanging Carbon dioxide Catalysts Catalytic activity Chemical analysis Chemical synthesis Hydrosilylation Infrared analysis Infrared spectroscopy NMR spectroscopy Silicon dioxide Spectrum analysis
title	Silica-supported Alkylammonium Formate Catalyst for Hydrosilylation of Carbon Dioxide
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