The effects of the oxygen content on the photoelectrochemical properties of LaFeO3 perovskite thin films obtained by pulsed laser deposition

The physical properties of perovskite oxides are strongly influenced by their stoichiometry and one of the key features of these materials is the tunability of their functionality by controlling the interplay between the compositional and structural properties. Here, the effects on the photoelectrochemical (PEC) water splitting properties of ferroelectric LaFeO 3 thin films obtained at different oxygen partial pressures during growth are reported in conjunction with the morphological, optical and structural features. The LaFeO 3 thin films have been deposited by pulsed laser deposition on Nb:SrTiO 3 substrates. The strong dependence of the photocurrent values J photo on the growth conditions is revealed by the photoelectrochemical measurements. Strong variations of the lateral coherence lengths L ‖ of LaFeO 3 /Nb:SrTiO 3 with the oxygen partial pressure values are noticed from the X-ray diffraction (XRD) analysis. All the films are heteroepitaxial with small tensile strain levels detected in the crystalline structure, but only for a narrow interval of oxygen partial pressures the LFO/STON thin films show high quality crystalline structure with large lateral coherence length L ‖ and photoelectrochemical currents.