Kinetics of Butadiene Polymerization in the Presence of the TiCl4-Al(i-C4H9)3 Catalytic System Physically Modified in Turbulent Flows: Results of Computational Experiments

The influence of the velocity of feeding the reaction mixture to a tubular turbulent diffuser-confuser apparatus and of the geometric parameters of the apparatus on the fields the flow turbulence kinetic energy and its dissipation rate was revealed in computational experiments with a model reaction,...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of applied chemistry 2019, Vol.92 (9), p.1200-1209
Hauptverfasser: Tereshchenko, K. A., Ulitin, N. V., Shiyan, D. A., Ziganshina, A. S., Zakharov, V. P.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The influence of the velocity of feeding the reaction mixture to a tubular turbulent diffuser-confuser apparatus and of the geometric parameters of the apparatus on the fields the flow turbulence kinetic energy and its dissipation rate was revealed in computational experiments with a model reaction, polymerization of butadiene in toluene in the presence of the TiCl 4 -Al( i -C 4 H 9 ) 3 catalytic system physically modified in turbulent flows. Correlation between the fields of the flow turbulence kinetic energy and its dissipation rate, on the one hand, and butadiene polymerization rate, on the other hand, is considered.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427219090039