Effect of the Nature of Organic Solvent on the Association of N-[3-(Dimethylamino)propyl](meth)acrylamides

Effect of the Nature of Organic Solvent on the Association of N-[3-(Dimethylamino)propyl](meth)acrylamides

The association of N -[3-(dimethylamino)propyl](meth)acrylamides in tetrachloromethane, tetrahydrofuran, and N, N -dimethylformamide has been studied by means of IR spectroscopy and quantum-chemical simulation at the B3LYP/6-31+G(d,p)/PCM level. The effect of the hydrogen bonding capacity of the sol...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of general chemistry 2019-09, Vol.89 (9), p.1787-1791
Hauptverfasser: Kamorina, S. I., Sadikov, A. Yu, Kamorin, D. M., Kazantsev, O. A., Rumyantsev, M. S., Korotaev, M. S., Postnikova, I. N.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Hydrogen bonding
Infrared spectroscopy
Organic chemistry
Quantum chemistry
Solvents
Tetrahydrofuran
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The association of N -[3-(dimethylamino)propyl](meth)acrylamides in tetrachloromethane, tetrahydrofuran, and N, N -dimethylformamide has been studied by means of IR spectroscopy and quantum-chemical simulation at the B3LYP/6-31+G(d,p)/PCM level. The effect of the hydrogen bonding capacity of the solvent on the degree of participation of N -[3-(dimethylamino)propyl](meth)acrylamides in hydrogen bonding with the formation of the amide-solvent type self-associates and heteroassociates has been elucidated.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036321909010X