Evidence of a cluster spin-glass state in B-site disordered perovskite SrTi0.5Mn0.5O3

•Substitution of 50% Mn4+ by Ti4+ results in B-site disordered SrTi0.5Mn0.5MnO3.•SrTi0.5Mn0.5MnO3 undergoes cluster spin glass state below 14 K.•Absence of long range ordering is confirm through neutron diffraction.•Dilute magnetism and competing interactions are responsible for observed behaviour....

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Veröffentlicht in:Journal of magnetism and magnetic materials 2019-12, Vol.492, p.165671, Article 165671
Hauptverfasser: Sharma, Shivani, Yadav, Poonam, Sau, Tusita, Yanda, Premakumar, Baker, Peter J., da Silva, Ivan, Sundaresan, A., Lalla, N.P.
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Sprache:eng
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Zusammenfassung:•Substitution of 50% Mn4+ by Ti4+ results in B-site disordered SrTi0.5Mn0.5MnO3.•SrTi0.5Mn0.5MnO3 undergoes cluster spin glass state below 14 K.•Absence of long range ordering is confirm through neutron diffraction.•Dilute magnetism and competing interactions are responsible for observed behaviour. SrTi0.5Mn0.5O3 (STMO) is a chemically disordered perovskite having random distribution of Ti and Mn over 1b site. Striking discrepancies about the structural and magnetic properties of STMO demand detail analysis which is addressed. To explore the magnetic ground state of STMO, static and dynamic magnetic properties were studied over a broad temperature range (2–300 K). The dc and ac magnetization shows a cusp like peak at Tf ~ 14 K, which exhibits field and frequency dependence. The thermoremanent magnetization is characterized by using stretched exponential function and characteristic time suggests the existence of spin clusters. Also, the other features observed in magnetic memory effect, muon spin resonance/rotation and neutron powder diffraction confirm the existence of cluster spin glass state in STMO, rather than the long-range ordered ground state. Intriguingly, the observed spin-relaxation can be attributed to the dilute magnetism due to non-magnetic doping at Mn-site and competing antiferromagnetic and ferromagnetic interactions resulting from the site disorder.
ISSN:0304-8853
1873-4766
DOI:10.1016/j.jmmm.2019.165671