Microwave‐Assisted Ruthenium(II)‐Catalyzed C−H/N−O Activation of N‐Methoxybenzamides with Alkynylsulfane

Microwave‐Assisted Ruthenium(II)‐Catalyzed C−H/N−O Activation of N‐Methoxybenzamides with Alkynylsulfane

An annulation of phenyl(phenylethynyl)sulfane and N‐methoxybenzamides through ruthenium C−H/N−O activation is reported. A wide variety of 4‐aryl‐3‐(aryl/alkylthio)isoquinolin‐1(2H)‐one derivatives are obtained in moderate to good yields. Microwave dinner: An annulation of phenyl(phenylethynyl)sulfan...

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Veröffentlicht in:Asian journal of organic chemistry 2019-10, Vol.8 (10), p.1830-1833
Hauptverfasser: Sarathkumar, Sundaramoorthi, Kavala, Veerababurao, Yao, Ching‐Fa
Format: Artikel
Sprache:eng
Schlagworte:
4-aryl-3-(aryl/alkylthio)isoquinolin-1(2H)-ones
Activation
alkynylsulfanes
Aromatic compounds
Chemical reactions
C−H activation
microwave chemistry
Organic chemistry
Ruthenium
Ruthenium compounds
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Zusammenfassung:An annulation of phenyl(phenylethynyl)sulfane and N‐methoxybenzamides through ruthenium C−H/N−O activation is reported. A wide variety of 4‐aryl‐3‐(aryl/alkylthio)isoquinolin‐1(2H)‐one derivatives are obtained in moderate to good yields. Microwave dinner: An annulation of phenyl(phenylethynyl)sulfane and N‐methoxybenzamide through ruthenium C−H/N−O activation is reported herein.
ISSN:2193-5807
2193-5815
DOI:10.1002/ajoc.201900383