Crystal Structure of Bis(μ-hydroxo)diiron(II) Complex with a Dinucleating Ligand Having a Butyl Linker

Crystal Structure of Bis(μ-hydroxo)diiron(II) Complex with a Dinucleating Ligand Having a Butyl Linker

The structure of the dinuclear Fe(II) complex [Fe2(OH)2(LBu)]2+ (1) was determined by X-ray crystallography, where LBu is N,N,N′,N′-tetrakis(6-methyl-2-pyridylmethyl)-1,4-diaminobutane. The compound crystallizes in a monoclinic space group, P21/a, with a = 21.678(3), b = 16.3791(16), c = 22.447(3)Å,...

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Veröffentlicht in:X-ray Structure Analysis Online 2019/02/10, Vol.35, pp.5-7
Hauptverfasser: SEKINO, Mio, FURUTACHI, Hideki, TASAKI, Kyosuke, ISHIKAWA, Takanao, FUJINAMI, Shuhei, AKINE, Shigehisa, SAKATA, Yoko, SUZUKI, Masatatsu, NOMURA, Takashi, OGURA, Takashi, KITAGAWA, Teizo
Format: Artikel
Sprache:eng
Schlagworte:
Coordination compounds
Crystal structure
Crystallography
Crystals
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Zusammenfassung:The structure of the dinuclear Fe(II) complex [Fe2(OH)2(LBu)]2+ (1) was determined by X-ray crystallography, where LBu is N,N,N′,N′-tetrakis(6-methyl-2-pyridylmethyl)-1,4-diaminobutane. The compound crystallizes in a monoclinic space group, P21/a, with a = 21.678(3), b = 16.3791(16), c = 22.447(3)Å, β = 111.522(2)°, Z = 4, V = 7414.5(14)Å3. The R1 [I > 2σ(I)] and wR2 (all data) values were 0.0474 and 0.1274, respectively, for all 16779 independent reflections. The complex has a bis(μ-hydroxo)diiron core structure.
ISSN:1883-3578
1883-3578
DOI:10.2116/xraystruct.35.5