Frequency Dispersion of the Electroelasticity Modulus in Aqueous Electrolyte Solutions
Friction coefficients β a and β b , relaxation times τ a , τ b , τ ab , and ∈(ω) for aqueous solutions of LiCl, NaCl, KCl, RbCl, CsCl are numerically calculated as functions of concentration c , density ρ, and temperature T in a wide range of frequencies ω using analytical expression for the electro...
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Veröffentlicht in: | Journal of structural chemistry 2019-09, Vol.60 (9), p.1421-1429 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | Friction coefficients β
a
and β
b
, relaxation times τ
a
, τ
b
, τ
ab
, and ∈(ω) for aqueous solutions of LiCl, NaCl, KCl, RbCl, CsCl are numerically calculated as functions of concentration
c
, density ρ, and temperature
T
in a wide range of frequencies ω using analytical expression for the electroelasticity modulus ∈(ω) obtained previously in the case of exponentially relaxing flows for a specific form of potential energy corresponding to the interaction between structural units of solution Φ
ab
(
r
) and the equilibrium radial distribution function
g
ab
(
r
). The obtained theoretical data are presented in the form of tables and graphs and are shown to be in a satisfactory agreement with experimental results. |
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ISSN: | 0022-4766 1573-8779 |
DOI: | 10.1134/S0022476619090063 |