Frequency Dispersion of the Electroelasticity Modulus in Aqueous Electrolyte Solutions

Friction coefficients β a and β b , relaxation times τ a , τ b , τ ab , and ∈(ω) for aqueous solutions of LiCl, NaCl, KCl, RbCl, CsCl are numerically calculated as functions of concentration c , density ρ, and temperature T in a wide range of frequencies ω using analytical expression for the electro...

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Veröffentlicht in:Journal of structural chemistry 2019-09, Vol.60 (9), p.1421-1429
Hauptverfasser: Odinaev, S., Akdodov, D. M., Idibegzoda, Kh. I.
Format: Artikel
Sprache:eng
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Zusammenfassung:Friction coefficients β a and β b , relaxation times τ a , τ b , τ ab , and ∈(ω) for aqueous solutions of LiCl, NaCl, KCl, RbCl, CsCl are numerically calculated as functions of concentration c , density ρ, and temperature T in a wide range of frequencies ω using analytical expression for the electroelasticity modulus ∈(ω) obtained previously in the case of exponentially relaxing flows for a specific form of potential energy corresponding to the interaction between structural units of solution Φ ab ( r ) and the equilibrium radial distribution function g ab ( r ). The obtained theoretical data are presented in the form of tables and graphs and are shown to be in a satisfactory agreement with experimental results.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476619090063