Bis-Hexaaquasodium Decaaqua-Monohydrogen-Hexasodium-Gadolinium-bis-(Nitrilo-Tris-Methylenephosphonate) Tetrahydrate: Synthesis, Structure, Chemical Bonding
Bis-hexaaquasodium decaaqua-monohydrogen-hexasodium-gadolinium-bis-(nitrilo-tris-methylenephosphonate) tetrahydrate [Na(H 2 O) 6 ] 2 [GdNa 6 H(H 2 O) 10 {N(CH 2 PO 3 } 2 ]·4H 2 O (space group P 2 1 / c, Z = 2, a = 11.8168(7) Å, b = 10.5403(9) Å, c = 19.8094(10) Å, β = 94.232(5)) has been synthesized...
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Veröffentlicht in: | Journal of structural chemistry 2019-09, Vol.60 (9), p.1385-1395 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | Bis-hexaaquasodium decaaqua-monohydrogen-hexasodium-gadolinium-bis-(nitrilo-tris-methylenephosphonate) tetrahydrate [Na(H
2
O)
6
]
2
[GdNa
6
H(H
2
O)
10
{N(CH
2
PO
3
}
2
]·4H
2
O (space group
P
2
1
/
c, Z
= 2,
a
= 11.8168(7) Å,
b
= 10.5403(9) Å,
c
= 19.8094(10) Å, β = 94.232(5)) has been synthesized and isolated. The Gd
3+
ion is coordinated in the configuration of an elongated rhombohedron in the environment of two acid residues {N(CH
2
PO
3
)
3
}. Two rhombohedron’s vertices distant from its center are occupied by nitrogen atoms, and six nearest vertices are occupied by oxygen atoms. Six sodium ions form inorganic bridges P-O-Na-O-P. The structure of the obtained complex is confirmed spectroscopically. XPS data indicate the formation of coordination bonds Gd-N and multiple bonds Gd-O. |
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ISSN: | 0022-4766 1573-8779 |
DOI: | 10.1134/S0022476619090038 |