Theoretical and FTIR Investigations of the Acetonitrile Hydrogenation Pathways on Platinum
The hydrogenation reaction of acetonitrile adsorbed on a platinum surface to produce amines has been investigated by theoretical and in situ infrared studies. An energetic, kinetics and vibrational analysis have been performed to unravel the elementary steps of the reaction and to clarify the mechan...
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| Veröffentlicht in: | Topics in catalysis 2019-09, Vol.62 (12-16), p.1076-1085 |
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| container_issue | 12-16 |
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| container_title | Topics in catalysis |
| container_volume | 62 |
| creator | Vogt, Lautaro Schulte, Erica Collins, Sebastián Quaino, Paola |
| description | The hydrogenation reaction of acetonitrile adsorbed on a platinum surface to produce amines has been investigated by theoretical and in situ infrared studies. An energetic, kinetics and vibrational analysis have been performed to unravel the elementary steps of the reaction and to clarify the mechanism. The comparison with the experiments allows us to identify an imine as a crucial intermediate for this reaction. |
| doi_str_mv | 10.1007/s11244-019-01194-x |
| format | Article |
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| issn | 1022-5528 1572-9028 |
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| subjects | Acetonitrile Amines Catalysis Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Hydrogenation Industrial Chemistry/Chemical Engineering Infrared analysis Original Paper Pharmacy Physical Chemistry Platinum Reaction kinetics |
| title | Theoretical and FTIR Investigations of the Acetonitrile Hydrogenation Pathways on Platinum |
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