Theoretical and FTIR Investigations of the Acetonitrile Hydrogenation Pathways on Platinum

The hydrogenation reaction of acetonitrile adsorbed on a platinum surface to produce amines has been investigated by theoretical and in situ infrared studies. An energetic, kinetics and vibrational analysis have been performed to unravel the elementary steps of the reaction and to clarify the mechan...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Topics in catalysis 2019-09, Vol.62 (12-16), p.1076-1085
Hauptverfasser:	Vogt, Lautaro, Schulte, Erica, Collins, Sebastián, Quaino, Paola
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Amines Catalysis Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Hydrogenation Industrial Chemistry/Chemical Engineering Infrared analysis Original Paper Pharmacy Physical Chemistry Platinum Reaction kinetics
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The hydrogenation reaction of acetonitrile adsorbed on a platinum surface to produce amines has been investigated by theoretical and in situ infrared studies. An energetic, kinetics and vibrational analysis have been performed to unravel the elementary steps of the reaction and to clarify the mechanism. The comparison with the experiments allows us to identify an imine as a crucial intermediate for this reaction.
ISSN:	1022-5528 1572-9028
DOI:	10.1007/s11244-019-01194-x