Copper based metal-organic coordination polymer for high-performance supercapacitors

[Display omitted] •Facile synthesis of copper based metal–organic coordination polymer (MOCP).•Cu-MOCP delivers specific capacitance of 217.3 F g−1 at 0.4 mA cm−2.•High stability as 95.5% capacity retains for 2000 cycles at 6.7 mA cm−2 for Cu-MOCP.•Improved capacitance of Cu-MOCP occurs by their mic...

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Veröffentlicht in:Materials letters 2019-07, Vol.247, p.48-51
Hauptverfasser: Prakash, S., Raj, J. Anandha, Muthuraja, P., Kalaignan, G. Paruthimal, Manisankar, P.
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Sprache:eng
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Zusammenfassung:[Display omitted] •Facile synthesis of copper based metal–organic coordination polymer (MOCP).•Cu-MOCP delivers specific capacitance of 217.3 F g−1 at 0.4 mA cm−2.•High stability as 95.5% capacity retains for 2000 cycles at 6.7 mA cm−2 for Cu-MOCP.•Improved capacitance of Cu-MOCP occurs by their microflower structure. Copper (Cu)-dipicolonic acid (DPA) based metal-organic coordination polymers (MOCPs) has been evaluated as an electrode material for supercapacitors. Cu-MOCP exhibits specific capacitance of 217.3 F g−1 at 0.4 mA cm−2 and superior capacitance retention of 95.5% after 2000 cycles at 6.7 mA cm−2 in 1.0 M NaOH electrolyte using galvanostatic study. It may arouse from the micro structure in Cu-MOCP that gives enough void for storage and diffusion of electrolyte, suggesting its promising electrode material for supercapacitors.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2019.03.006