Magnetocaloric properties of (Gd1-xErx)3Ru alloys and their composites
We present magnetization, specific heat and magnetocaloric effect results for the compounds (Gd1-xErx)3Ru, with x = 0.05, 0.1, 0.2 and 1. As Er concentration increases we observe a significant reduction of the transition temperature from 52 K to 8.1 K and a change from first order ferromagnetic to s...
Gespeichert in:
Veröffentlicht in: | Journal of alloys and compounds 2019-09, Vol.803, p.1178-1183 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | We present magnetization, specific heat and magnetocaloric effect results for the compounds (Gd1-xErx)3Ru, with x = 0.05, 0.1, 0.2 and 1. As Er concentration increases we observe a significant reduction of the transition temperature from 52 K to 8.1 K and a change from first order ferromagnetic to second order antiferromagnetic behavior. Despite the magnetic arrangement changes, the magnetocaloric potential remains high and a composite formed with these compounds is proposed to achieve temperatures of 20 K starting from nitrogen boiling point. The magnetic entropy variation and adiabatic temperature change of the composite were directly measured presenting a plateau between 20 K and 77 K with values higher than 6 J/kg.K and 3 K respectively for a magnetic field variation of 5 T.
•Structural, magnetic and calorimetric properties for the (Gd1-xErx)3Ru series.•Outline of a composite for cryogenic refrigeration from liquid nitrogen temperature.•Direct measurements of the magnetocaloric properties of a multi-compound assembly. |
---|---|
ISSN: | 0925-8388 1873-4669 |
DOI: | 10.1016/j.jallcom.2019.06.265 |