Stepwise and hysteretic sorption of CO2 in polycatenated metal–organic frameworks

Stepwise and hysteretic sorption of CO2 in polycatenated metal–organic frameworks

Two polycatenated metal–organic framework materials with different metal centers (Zn2+ for 1 and Cd2+ for 2) were synthesized, which underwent pronounced framework phase transition upon desolvation, and exhibited uncommon temperature-dependent stepwise adsorption and hysteretic desorption of CO2 aro...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:CrystEngComm 2019, Vol.21 (32), p.4696-4700
Hauptverfasser: Di-Ming, Chen, Xue-Jing, Zhang
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Crystallography
Hysteresis
Metal-organic frameworks
Phase transitions
Sorption
Temperature dependence
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Two polycatenated metal–organic framework materials with different metal centers (Zn2+ for 1 and Cd2+ for 2) were synthesized, which underwent pronounced framework phase transition upon desolvation, and exhibited uncommon temperature-dependent stepwise adsorption and hysteretic desorption of CO2 around room temperature.
ISSN:1466-8033
DOI:10.1039/c9ce00760a