Phase structure, Raman spectroscopic, microstructure and dielectric properties of (K0.5Na0.5)NbO3–Bi(Li0.5Nb0.5)O3 lead-free ceramics

(1- x )(K 0.5 Na 0.5 )NbO 3 – x Bi(Li 0.5 Nb 0.5 )O 3 [(1- x )KNN– x BLN, 0 ≤  x  ≤ 0.02] dielectric ceramics were synthesized by an ordinary sintering technique. The effects of Bi(Li 0.5 Nb 0.5 )O 3 addition on the phase structure, microstructure and dielectric properties of KNN ceramics were studi...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2019-09, Vol.125 (9), p.1-10, Article 608
Hauptverfasser: Shi, Junpeng, Yu, Yujing, Chen, Xiuli, Liu, Gaofeng, Jiang, Xinyu, Liang, Jinling, Ling, Jiajie, Xu, Mingzhao, Zhou, Huanfu
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Sprache:eng
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Zusammenfassung:(1- x )(K 0.5 Na 0.5 )NbO 3 – x Bi(Li 0.5 Nb 0.5 )O 3 [(1- x )KNN– x BLN, 0 ≤  x  ≤ 0.02] dielectric ceramics were synthesized by an ordinary sintering technique. The effects of Bi(Li 0.5 Nb 0.5 )O 3 addition on the phase structure, microstructure and dielectric properties of KNN ceramics were studied. The phase structure of ceramics shifted from the orthorhombic to pseudo-cubic phase structure with increasing the content of Bi(Li 0.5 Nb 0.5 )O 3 . The addition of Bi(Li 0.5 Nb 0.5 )O 3 depressed the transition temperature of the orthogonal and tetragonal phases, which is a benefit to the thermal stability of KNN ceramics. Especially, as x  = 0.01, the ceramics have a high relative permittivity ε r (~ 1557), low dielectric loss tan δ (
ISSN:0947-8396
1432-0630
DOI:10.1007/s00339-019-2860-x