Novel electroconducting polypyrrole/carbon nanotube/alginate nanocomposites synthesized by hydrogen peroxide-mediated emulsion pathway
[Display omitted] •Novel electroconducting PPy/CNT/alginate nanocomposites were synthesized through in situ chemical polymerization in micellar media.•The method involves H2O2 and small amount of SDS as a green approach to form a three-dimensional structure with well-connected domains.•The synergist...
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Veröffentlicht in: | Synthetic metals 2019-07, Vol.253, p.100-109 |
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Format: | Artikel |
Sprache: | eng |
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•Novel electroconducting PPy/CNT/alginate nanocomposites were synthesized through in situ chemical polymerization in micellar media.•The method involves H2O2 and small amount of SDS as a green approach to form a three-dimensional structure with well-connected domains.•The synergistic combination of pristine CNT and alginate improves the conductivity and stability of PPy-based colloids.•A metoprolol-loaded platform was obtained by the confinement of the synthesized nanocomposite into an alginate network.•The hydrogel matrix produces a hindering effect on drug release in passive conditions.
The development of Green-based methods for preparing polypyrrole (PPy)-containing materials with optimal electroactivity still remains a challenge. We herein report a new green approach for the preparation of PPy/carbon nanotube/alginate multifunctional nanocomposites through H2O2 oxidation in micellar medium. The polymerization conditions were systematically varied to optimize the reaction yield and the material electroconductivity. The pre-polymerization emulsion system was studied by contact angle measurements and dynamic light scattering. The results of zeta potential characterization, field-emission scanning electron and atomic force microscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and electrochemical impedance spectroscopy are discussed in detail, and a consistent mechanism for the nanocomposite formation is proposed. Interestingly, the synergistic combination of pristine carbon nanotubes and the alginate improves the conductivity and stability of PPy-based colloids. Furthermore, a metoprolol-loaded platform, obtained by the confinement of the synthesized nanocomposite into an alginate network, revealed a cumulative release lesser than 10% after five hours of delivery under passive conditions. This behavior seems to be promising to overcome the undesired burst release in stimulus-controlled drug delivery. |
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ISSN: | 0379-6779 1879-3290 |
DOI: | 10.1016/j.synthmet.2019.05.006 |