Metal–Organic Framework‐Activated Carbon Composite Materials for the Removal of Ammonia from Contaminated Airstreams

Metal–organic frameworks (MOFs) are a class of porous materials that show promise in the removal of toxic industrial chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF‐activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM‐17‐OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment. Crystals in coal: A new series of MOF‐activated carbon composite materials are synthesised, using the copper MOF: STAM‐17‐OEt and commercially available BPL activated carbon. STAM‐17‐OEt is grown inside BPL carbon at three loadings to provide a series of granular materials that display excellent gas adsorption properties and water stability.