Mechanisms of Formation of Macrodynamic Thermal Properties of Crystallizing Polymer Nanocomposites

This paper considers the main elements of the mechanisms of formation of macrodynamic thermal properties of nanocomposite polymer materials (NCPMs) based on polymerization, polycondensation thermoplastics, and ultrafine metallic particles. It is shown that a new, higher level of thermal properties in NCPMs is formed as a result of intramatrix interdependent physicochemical interactions between matrix thermoplastic and nanoparticles of an ultrafine metallic medium (UFM). The implementation of intramatrix physicochemical interactions of the components of the thermoplastic + UFM heterogeneous system in NCPMs as a manifestation of nanotechnology is effective, when the matrix thermoplastic has sufficient morphological potential and the nanomodifier has a spectrum of specific properties.