Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding

The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Cellulose (London) 2016-02, Vol.23 (1), p.823-836
Hauptverfasser: Lackinger, Elisabeth, Hettegger, Hubert, Schwaiger, Lorenz, Zweckmair, Thomas, Sartori, Jürgen, Potthast, Antje, Rosenau, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 836
container_issue 1
container_start_page 823
container_title Cellulose (London)
container_volume 23
creator Lackinger, Elisabeth
Hettegger, Hubert
Schwaiger, Lorenz
Zweckmair, Thomas
Sartori, Jürgen
Potthast, Antje
Rosenau, Thomas
description The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the largest part of ASA to be bound only by physisorption and only a rather small fraction, typically about 0.5 %, to be covalently attached by ester bonds. In the case of MSOHO, the covalent binding was only slightly higher, with about 3 % of the total amount being covalently linked. In both cases, covalently bound sizing agents were found to be almost uniformly distributed over the whole DP range of the cellulose as seen by carboxyl-selective fluorescence labeling in combination with size exclusion chromatography (“FDAM method”).
doi_str_mv 10.1007/s10570-015-0794-9
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2259929249</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2259929249</sourcerecordid><originalsourceid>FETCH-LOGICAL-c386t-b22dabfd0661efde8d24c4868057910a51954d8af929a9ed23aa1b537d1f8c883</originalsourceid><addsrcrecordid>eNp1kctKxDAUhoMoOF4ewF3AdTVJb4k7EW8wqAsFd-G0OZ3pUJuadCq68iHc-nI-iakzIC5cBU6-7z8hPyEHnB1xxvJjz1mas4jxNGK5SiK1QSY8zUUkpXjcJBOmMhUxEattsuP9gjGmcsEn5PPGDtjQDjp01NdvdTujMMO297QAj4baljps8QWKBv0RvQPXU3kyjvs50qJuzagUOIehto7aKuBQ9vWAf-O-3j9G4XmJvq-DHcDSDtCEOzqg80tPwXjruh91nbtHtipoPO6vz13ycHF-f3YVTW8vr89Op1EZy6yPCiEMFJVhWcaxMiiNSMpEZjL8ieIMUq7SxEiolFCg0IgYgBdpnBteyVLKeJccrnI7Z39eqBd26dqwUguRqqCJRAWKr6jSWe8dVrpz9RO4V82ZHlvQqxZ0aEGPLejRESvHB7adoftN_l_6BhNgjoM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259929249</pqid></control><display><type>article</type><title>Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding</title><source>Springer Nature - Complete Springer Journals</source><creator>Lackinger, Elisabeth ; Hettegger, Hubert ; Schwaiger, Lorenz ; Zweckmair, Thomas ; Sartori, Jürgen ; Potthast, Antje ; Rosenau, Thomas</creator><creatorcontrib>Lackinger, Elisabeth ; Hettegger, Hubert ; Schwaiger, Lorenz ; Zweckmair, Thomas ; Sartori, Jürgen ; Potthast, Antje ; Rosenau, Thomas</creatorcontrib><description>The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the largest part of ASA to be bound only by physisorption and only a rather small fraction, typically about 0.5 %, to be covalently attached by ester bonds. In the case of MSOHO, the covalent binding was only slightly higher, with about 3 % of the total amount being covalently linked. In both cases, covalently bound sizing agents were found to be almost uniformly distributed over the whole DP range of the cellulose as seen by carboxyl-selective fluorescence labeling in combination with size exclusion chromatography (“FDAM method”).</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-015-0794-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Adsorptivity ; Alkenes ; Anhydrides ; Binding ; Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Covalence ; Fluorescence ; Glass ; Natural Materials ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer Sciences ; Size exclusion chromatography ; Sizing ; Sunflower oil ; Sunflowers ; Sustainable Development</subject><ispartof>Cellulose (London), 2016-02, Vol.23 (1), p.823-836</ispartof><rights>Springer Science+Business Media Dordrecht 2015</rights><rights>Cellulose is a copyright of Springer, (2015). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-b22dabfd0661efde8d24c4868057910a51954d8af929a9ed23aa1b537d1f8c883</citedby><cites>FETCH-LOGICAL-c386t-b22dabfd0661efde8d24c4868057910a51954d8af929a9ed23aa1b537d1f8c883</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-015-0794-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-015-0794-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Lackinger, Elisabeth</creatorcontrib><creatorcontrib>Hettegger, Hubert</creatorcontrib><creatorcontrib>Schwaiger, Lorenz</creatorcontrib><creatorcontrib>Zweckmair, Thomas</creatorcontrib><creatorcontrib>Sartori, Jürgen</creatorcontrib><creatorcontrib>Potthast, Antje</creatorcontrib><creatorcontrib>Rosenau, Thomas</creatorcontrib><title>Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the largest part of ASA to be bound only by physisorption and only a rather small fraction, typically about 0.5 %, to be covalently attached by ester bonds. In the case of MSOHO, the covalent binding was only slightly higher, with about 3 % of the total amount being covalently linked. In both cases, covalently bound sizing agents were found to be almost uniformly distributed over the whole DP range of the cellulose as seen by carboxyl-selective fluorescence labeling in combination with size exclusion chromatography (“FDAM method”).</description><subject>Adsorptivity</subject><subject>Alkenes</subject><subject>Anhydrides</subject><subject>Binding</subject><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Covalence</subject><subject>Fluorescence</subject><subject>Glass</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Size exclusion chromatography</subject><subject>Sizing</subject><subject>Sunflower oil</subject><subject>Sunflowers</subject><subject>Sustainable Development</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kctKxDAUhoMoOF4ewF3AdTVJb4k7EW8wqAsFd-G0OZ3pUJuadCq68iHc-nI-iakzIC5cBU6-7z8hPyEHnB1xxvJjz1mas4jxNGK5SiK1QSY8zUUkpXjcJBOmMhUxEattsuP9gjGmcsEn5PPGDtjQDjp01NdvdTujMMO297QAj4baljps8QWKBv0RvQPXU3kyjvs50qJuzagUOIehto7aKuBQ9vWAf-O-3j9G4XmJvq-DHcDSDtCEOzqg80tPwXjruh91nbtHtipoPO6vz13ycHF-f3YVTW8vr89Op1EZy6yPCiEMFJVhWcaxMiiNSMpEZjL8ieIMUq7SxEiolFCg0IgYgBdpnBteyVLKeJccrnI7Z39eqBd26dqwUguRqqCJRAWKr6jSWe8dVrpz9RO4V82ZHlvQqxZ0aEGPLejRESvHB7adoftN_l_6BhNgjoM</recordid><startdate>20160201</startdate><enddate>20160201</enddate><creator>Lackinger, Elisabeth</creator><creator>Hettegger, Hubert</creator><creator>Schwaiger, Lorenz</creator><creator>Zweckmair, Thomas</creator><creator>Sartori, Jürgen</creator><creator>Potthast, Antje</creator><creator>Rosenau, Thomas</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20160201</creationdate><title>Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding</title><author>Lackinger, Elisabeth ; Hettegger, Hubert ; Schwaiger, Lorenz ; Zweckmair, Thomas ; Sartori, Jürgen ; Potthast, Antje ; Rosenau, Thomas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-b22dabfd0661efde8d24c4868057910a51954d8af929a9ed23aa1b537d1f8c883</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Adsorptivity</topic><topic>Alkenes</topic><topic>Anhydrides</topic><topic>Binding</topic><topic>Bioorganic Chemistry</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Covalence</topic><topic>Fluorescence</topic><topic>Glass</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Size exclusion chromatography</topic><topic>Sizing</topic><topic>Sunflower oil</topic><topic>Sunflowers</topic><topic>Sustainable Development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lackinger, Elisabeth</creatorcontrib><creatorcontrib>Hettegger, Hubert</creatorcontrib><creatorcontrib>Schwaiger, Lorenz</creatorcontrib><creatorcontrib>Zweckmair, Thomas</creatorcontrib><creatorcontrib>Sartori, Jürgen</creatorcontrib><creatorcontrib>Potthast, Antje</creatorcontrib><creatorcontrib>Rosenau, Thomas</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied &amp; Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lackinger, Elisabeth</au><au>Hettegger, Hubert</au><au>Schwaiger, Lorenz</au><au>Zweckmair, Thomas</au><au>Sartori, Jürgen</au><au>Potthast, Antje</au><au>Rosenau, Thomas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2016-02-01</date><risdate>2016</risdate><volume>23</volume><issue>1</issue><spage>823</spage><epage>836</epage><pages>823-836</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the largest part of ASA to be bound only by physisorption and only a rather small fraction, typically about 0.5 %, to be covalently attached by ester bonds. In the case of MSOHO, the covalent binding was only slightly higher, with about 3 % of the total amount being covalently linked. In both cases, covalently bound sizing agents were found to be almost uniformly distributed over the whole DP range of the cellulose as seen by carboxyl-selective fluorescence labeling in combination with size exclusion chromatography (“FDAM method”).</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-015-0794-9</doi><tpages>14</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0969-0239
ispartof Cellulose (London), 2016-02, Vol.23 (1), p.823-836
issn 0969-0239
1572-882X
language eng
recordid cdi_proquest_journals_2259929249
source Springer Nature - Complete Springer Journals
subjects Adsorptivity
Alkenes
Anhydrides
Binding
Bioorganic Chemistry
Cellulose
Ceramics
Chemistry
Chemistry and Materials Science
Composites
Covalence
Fluorescence
Glass
Natural Materials
Organic Chemistry
Original Paper
Physical Chemistry
Polymer Sciences
Size exclusion chromatography
Sizing
Sunflower oil
Sunflowers
Sustainable Development
title Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-15T16%3A32%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Novel%20paper%20sizing%20agents%20based%20on%20renewables.%20Part%208:%20on%20the%20binding%20behavior%20of%20reactive%20sizing%20agents%E2%80%94the%20question%20of%20covalent%20versus%20adsorptive%20binding&rft.jtitle=Cellulose%20(London)&rft.au=Lackinger,%20Elisabeth&rft.date=2016-02-01&rft.volume=23&rft.issue=1&rft.spage=823&rft.epage=836&rft.pages=823-836&rft.issn=0969-0239&rft.eissn=1572-882X&rft_id=info:doi/10.1007/s10570-015-0794-9&rft_dat=%3Cproquest_cross%3E2259929249%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2259929249&rft_id=info:pmid/&rfr_iscdi=true