Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding
The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast...
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Veröffentlicht in: | Cellulose (London) 2016-02, Vol.23 (1), p.823-836 |
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creator | Lackinger, Elisabeth Hettegger, Hubert Schwaiger, Lorenz Zweckmair, Thomas Sartori, Jürgen Potthast, Antje Rosenau, Thomas |
description | The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the largest part of ASA to be bound only by physisorption and only a rather small fraction, typically about 0.5 %, to be covalently attached by ester bonds. In the case of MSOHO, the covalent binding was only slightly higher, with about 3 % of the total amount being covalently linked. In both cases, covalently bound sizing agents were found to be almost uniformly distributed over the whole DP range of the cellulose as seen by carboxyl-selective fluorescence labeling in combination with size exclusion chromatography (“FDAM method”). |
doi_str_mv | 10.1007/s10570-015-0794-9 |
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In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the largest part of ASA to be bound only by physisorption and only a rather small fraction, typically about 0.5 %, to be covalently attached by ester bonds. In the case of MSOHO, the covalent binding was only slightly higher, with about 3 % of the total amount being covalently linked. In both cases, covalently bound sizing agents were found to be almost uniformly distributed over the whole DP range of the cellulose as seen by carboxyl-selective fluorescence labeling in combination with size exclusion chromatography (“FDAM method”).</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-015-0794-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Adsorptivity ; Alkenes ; Anhydrides ; Binding ; Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Covalence ; Fluorescence ; Glass ; Natural Materials ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer Sciences ; Size exclusion chromatography ; Sizing ; Sunflower oil ; Sunflowers ; Sustainable Development</subject><ispartof>Cellulose (London), 2016-02, Vol.23 (1), p.823-836</ispartof><rights>Springer Science+Business Media Dordrecht 2015</rights><rights>Cellulose is a copyright of Springer, (2015). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-b22dabfd0661efde8d24c4868057910a51954d8af929a9ed23aa1b537d1f8c883</citedby><cites>FETCH-LOGICAL-c386t-b22dabfd0661efde8d24c4868057910a51954d8af929a9ed23aa1b537d1f8c883</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-015-0794-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-015-0794-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Lackinger, Elisabeth</creatorcontrib><creatorcontrib>Hettegger, Hubert</creatorcontrib><creatorcontrib>Schwaiger, Lorenz</creatorcontrib><creatorcontrib>Zweckmair, Thomas</creatorcontrib><creatorcontrib>Sartori, Jürgen</creatorcontrib><creatorcontrib>Potthast, Antje</creatorcontrib><creatorcontrib>Rosenau, Thomas</creatorcontrib><title>Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>The binding mechanisms of two reactive sizing agents, alkenyl succinic anhydride (ASA) and maleated sunflower oil high-oleic (MSOHO), with cellulose were studied. While ASA is produced from olefins out of fossil resources, MSOHO is a green sizing agent based on renewable plant materials. In contrast to common assumptions, that ASA is mostly covalently bound to cellulose, this study showed the largest part of ASA to be bound only by physisorption and only a rather small fraction, typically about 0.5 %, to be covalently attached by ester bonds. In the case of MSOHO, the covalent binding was only slightly higher, with about 3 % of the total amount being covalently linked. In both cases, covalently bound sizing agents were found to be almost uniformly distributed over the whole DP range of the cellulose as seen by carboxyl-selective fluorescence labeling in combination with size exclusion chromatography (“FDAM method”).</description><subject>Adsorptivity</subject><subject>Alkenes</subject><subject>Anhydrides</subject><subject>Binding</subject><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Covalence</subject><subject>Fluorescence</subject><subject>Glass</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Size exclusion chromatography</subject><subject>Sizing</subject><subject>Sunflower oil</subject><subject>Sunflowers</subject><subject>Sustainable Development</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kctKxDAUhoMoOF4ewF3AdTVJb4k7EW8wqAsFd-G0OZ3pUJuadCq68iHc-nI-iakzIC5cBU6-7z8hPyEHnB1xxvJjz1mas4jxNGK5SiK1QSY8zUUkpXjcJBOmMhUxEattsuP9gjGmcsEn5PPGDtjQDjp01NdvdTujMMO297QAj4baljps8QWKBv0RvQPXU3kyjvs50qJuzagUOIehto7aKuBQ9vWAf-O-3j9G4XmJvq-DHcDSDtCEOzqg80tPwXjruh91nbtHtipoPO6vz13ycHF-f3YVTW8vr89Op1EZy6yPCiEMFJVhWcaxMiiNSMpEZjL8ieIMUq7SxEiolFCg0IgYgBdpnBteyVLKeJccrnI7Z39eqBd26dqwUguRqqCJRAWKr6jSWe8dVrpz9RO4V82ZHlvQqxZ0aEGPLejRESvHB7adoftN_l_6BhNgjoM</recordid><startdate>20160201</startdate><enddate>20160201</enddate><creator>Lackinger, Elisabeth</creator><creator>Hettegger, Hubert</creator><creator>Schwaiger, Lorenz</creator><creator>Zweckmair, Thomas</creator><creator>Sartori, Jürgen</creator><creator>Potthast, Antje</creator><creator>Rosenau, Thomas</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20160201</creationdate><title>Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding</title><author>Lackinger, Elisabeth ; Hettegger, Hubert ; Schwaiger, Lorenz ; Zweckmair, Thomas ; Sartori, Jürgen ; Potthast, Antje ; Rosenau, Thomas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-b22dabfd0661efde8d24c4868057910a51954d8af929a9ed23aa1b537d1f8c883</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Adsorptivity</topic><topic>Alkenes</topic><topic>Anhydrides</topic><topic>Binding</topic><topic>Bioorganic Chemistry</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Covalence</topic><topic>Fluorescence</topic><topic>Glass</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Size exclusion chromatography</topic><topic>Sizing</topic><topic>Sunflower oil</topic><topic>Sunflowers</topic><topic>Sustainable Development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lackinger, Elisabeth</creatorcontrib><creatorcontrib>Hettegger, Hubert</creatorcontrib><creatorcontrib>Schwaiger, Lorenz</creatorcontrib><creatorcontrib>Zweckmair, Thomas</creatorcontrib><creatorcontrib>Sartori, Jürgen</creatorcontrib><creatorcontrib>Potthast, Antje</creatorcontrib><creatorcontrib>Rosenau, Thomas</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied & Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lackinger, Elisabeth</au><au>Hettegger, Hubert</au><au>Schwaiger, Lorenz</au><au>Zweckmair, Thomas</au><au>Sartori, Jürgen</au><au>Potthast, Antje</au><au>Rosenau, Thomas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel paper sizing agents based on renewables. 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subjects | Adsorptivity Alkenes Anhydrides Binding Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Composites Covalence Fluorescence Glass Natural Materials Organic Chemistry Original Paper Physical Chemistry Polymer Sciences Size exclusion chromatography Sizing Sunflower oil Sunflowers Sustainable Development |
title | Novel paper sizing agents based on renewables. Part 8: on the binding behavior of reactive sizing agents—the question of covalent versus adsorptive binding |
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