Luminescence of Cu+ in halosulphate phosphor

Ultraviolet photo-excited luminescence from Cu-doped halosulphate phosphors has been investigated. The intense emission of the spectrum is assigned to electronic transitions 3d⁹4s¹ → 3d¹⁰ in Cu⁺ ions. Increase in photoluminescence (PL) peak intensity suggesting that Cu plays an important role in PL...

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Veröffentlicht in:Journal of materials science 2008-05, Vol.43 (9), p.3189-3196
Hauptverfasser: Dhoble, S. J, Gedam, S. C, Nagpure, I. M, Godbole, S. V, Bhide, M. K, Moharil, S. V
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Sprache:eng
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Zusammenfassung:Ultraviolet photo-excited luminescence from Cu-doped halosulphate phosphors has been investigated. The intense emission of the spectrum is assigned to electronic transitions 3d⁹4s¹ → 3d¹⁰ in Cu⁺ ions. Increase in photoluminescence (PL) peak intensity suggesting that Cu plays an important role in PL emission in the present matrix. However, limited hosts with Cu⁺ as luminescence center were studied due to difficulties in incorporating it in a luminescence form. Cu-doped halosulphate phosphors were synthesized by wet chemical method. X-ray diffraction and PL characterization of phosphors has been reported in this article. The article discusses the luminescence of Cu⁺ and the simple method of incorporation in various new hosts.
ISSN:0022-2461
1573-4803
DOI:10.1007/s10853-008-2498-0