Hydrophobic mesoporous silica applied in GC separation of hexene isomers

A novel CH 3 -functionalized mesoporous silica material (PTM) with nearly spherical morphology was synthesized by a one-step synthesis route using polymethylhydrosiloxane and tetraethoxylsilane in the presence of triblock copolymer P123 as structure-directing agent. Thus-obtained material possessed...

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Veröffentlicht in:Journal of sol-gel science and technology 2010-10, Vol.56 (1), p.93-98
Hauptverfasser: Zhao, Yanling, Xu, Yao, Wu, Dong, Wei, Wei, Sun, Yuhan, Al-Arifi, Abdullah S. N., Aouak, Taieb, Al-Othman, Zeid Abdullah
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Sprache:eng
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Zusammenfassung:A novel CH 3 -functionalized mesoporous silica material (PTM) with nearly spherical morphology was synthesized by a one-step synthesis route using polymethylhydrosiloxane and tetraethoxylsilane in the presence of triblock copolymer P123 as structure-directing agent. Thus-obtained material possessed highly-ordered mesopore arrays and texture with highly CH 3 -functionalized surface. As compared with pure siliceous SBA-15, PTM showed the high performance for gas chromatographic separation of hexene isomers.
ISSN:0928-0707
1573-4846
DOI:10.1007/s10971-010-2280-z