The low-temperature water–gas shift reaction catalyzed by sodium-carbonate-activated ruthenium mono(bipyridine)/SiO2 complexes

The low-temperature water–gas shift reaction catalyzed by sodium-carbonate-activated ruthenium mono(bipyridine)/SiO2 complexes

The effect of a new catalyst activation method on the catalytic activities of several chlorine-containing ruthenium mono(bipyridine) carbonyl complexes in the water–gas shift reaction (WGSR) was studied. The chemical activation of the silica-supported complexes by a sodium carbonate/methanol solutio...

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Veröffentlicht in:Catalysis letters 2000-01, Vol.70 (3-4), p.123-125
Hauptverfasser: Luukkanen, Saija, Haukka, Matti, Kallinen, Mirja, Pakkanen, Tapani A
Format: Artikel
Sprache:eng
Schlagworte:
Activated carbon
Activation
Carbonyls
Catalysis
Catalysts
Chlorine
Low temperature
Organic chemistry
Ruthenium
Shift reaction
Silicon dioxide
Sodium carbonate
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Zusammenfassung:The effect of a new catalyst activation method on the catalytic activities of several chlorine-containing ruthenium mono(bipyridine) carbonyl complexes in the water–gas shift reaction (WGSR) was studied. The chemical activation of the silica-supported complexes by a sodium carbonate/methanol solution under CO atmosphere produced highly active low-temperature water–gas shift reaction catalysts.
ISSN:1011-372X
1572-879X
DOI:10.1023/A:1018881100163