Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid

Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid

The oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and benzoquinone in the presence of perchloric acid was studied. Tricyclodecenone in high selectivity (85–98%) at a conversion of dicyclopentadiene up to 76% was obtained. The kinetic model assumed the significant inhibition compl...

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Veröffentlicht in:Catalysis letters 2000-01, Vol.69 (1-2), p.103-107
Hauptverfasser: SKUMOV, M, BALBOLOV, E
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
Oxidation
Palladium
Perchloric acid
Quinones
Selectivity
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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BALBOLOV, E
description The oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and benzoquinone in the presence of perchloric acid was studied. Tricyclodecenone in high selectivity (85–98%) at a conversion of dicyclopentadiene up to 76% was obtained. The kinetic model assumed the significant inhibition complexation between dicyclopentadiene and tricyclodecenone with the catalytic species.
doi_str_mv 10.1023/A:1019053402854
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subjects Catalysis
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
Oxidation
Palladium
Perchloric acid
Quinones
Selectivity
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid
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