Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid

Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid

The oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and benzoquinone in the presence of perchloric acid was studied. Tricyclodecenone in high selectivity (85–98%) at a conversion of dicyclopentadiene up to 76% was obtained. The kinetic model assumed the significant inhibition compl...

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Veröffentlicht in:Catalysis letters 2000-01, Vol.69 (1-2), p.103-107
Hauptverfasser: SKUMOV, M, BALBOLOV, E
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
Oxidation
Palladium
Perchloric acid
Quinones
Selectivity
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Zusammenfassung:The oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and benzoquinone in the presence of perchloric acid was studied. Tricyclodecenone in high selectivity (85–98%) at a conversion of dicyclopentadiene up to 76% was obtained. The kinetic model assumed the significant inhibition complexation between dicyclopentadiene and tricyclodecenone with the catalytic species.
ISSN:1011-372X
1572-879X
DOI:10.1023/A:1019053402854