Activity of vanadium magnesium oxide supported catalysts in the dehydrogenation of isobutane

The activity of the vanadium magnesium binary oxides supported on Cact, SiO2, γ-Al2O3 and ZnO in the dehydrogenation of isobutane to isobutene under the carbon dioxide or inert gas atmosphere was investigated. The highest isobutene yield (34.8%) was obtained over active carbon supported catalyst. Th...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Catalysis letters 2006-10, Vol.111 (1-2), p.79-85
Hauptverfasser:	OGONOWSKI, Jan, SKRZYNSKA, Elzbieta
Format:	Artikel
Sprache:	eng
Schlagworte:	Activated carbon Aluminum oxide Ammonia Carbon Carbon dioxide Catalysis Catalysts Chemistry Dehydrogenation Exact sciences and technology Gasification General and physical chemistry Magnesium oxide Rare gases Regeneration Silicon dioxide Superconductors (materials) Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Transitional aluminas Vanadium Zinc oxide
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The activity of the vanadium magnesium binary oxides supported on Cact, SiO2, γ-Al2O3 and ZnO in the dehydrogenation of isobutane to isobutene under the carbon dioxide or inert gas atmosphere was investigated. The highest isobutene yield (34.8%) was obtained over active carbon supported catalyst. The role of carbon dioxide in the dehydrogenation process was determined on the basis of additional tests: the RWGS reaction, gasification of coke and regeneration of partially reduced catalysts. The temperature-programmed techniques (TPR-H2, TPD-NH3 and TPD-CO2) were used to characterize the catalysts.
ISSN:	1011-372X 1572-879X
DOI:	10.1007/s10562-006-0132-9