Coordination of CrIII(salen) on functionalised silica for asymmetric ring opening reactions of epoxides

The heterogeneous asymmetric ring opening (ARO) ofmeso-epoxides with trimethylsilylazide (TMSN3) catalysed by a Cr(salen) catalyst coordinated on an aminopropyl functionalised silica material combines good enantioselectivities with high conversions and suffers low leaching (

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Bibliographische Detailangaben
Veröffentlicht in:	Catalysis letters 2004-09, Vol.97 (3-4), p.125-129
Hauptverfasser:	DIOOS, Bart M. L, GEURTS, Wouter A, JACOBS, Pierre A
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemistry Exact sciences and technology General and physical chemistry Leaching Ring opening Silicon dioxide Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Beschreibung
Zusammenfassung:	The heterogeneous asymmetric ring opening (ARO) ofmeso-epoxides with trimethylsilylazide (TMSN3) catalysed by a Cr(salen) catalyst coordinated on an aminopropyl functionalised silica material combines good enantioselectivities with high conversions and suffers low leaching (
ISSN:	1011-372X 1572-879X
DOI:	10.1023/B:CATL.0000038573.81490.03