Nitrous Oxide Decomposition Over MCO₃-Co₃O₄ (M = Ca, Sr, Ba) Catalysts

In this paper, nitrous oxide decomposition over a series of MCO₃-Co₃O₄ (M = Ca, Sr, Ba) catalysts having M/Co ratios of 0.1-0.4 has been studied. The various catalysts were characterized using thermal (TGA, DTA), XRD, IR and N₂ sorption techniques. N₂O decomposition activity was found to be dependen...

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Veröffentlicht in:Catalysis letters 2009-10, Vol.132 (3-4), p.299-310
Hauptverfasser: Abu-Zied, B. M, Soliman, S. A
Format: Artikel
Sprache:eng
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Zusammenfassung:In this paper, nitrous oxide decomposition over a series of MCO₃-Co₃O₄ (M = Ca, Sr, Ba) catalysts having M/Co ratios of 0.1-0.4 has been studied. The various catalysts were characterized using thermal (TGA, DTA), XRD, IR and N₂ sorption techniques. N₂O decomposition activity was found to be dependent on the type of the alkaline earth cation, the M/Co ratio, cobalt oxide crystallites sizes, and the calcination temperature.
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-009-0158-x