Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols
Various epoxides and aziridines undergo smooth ring-opening with water in presence of 10 mol% of bismuth triflate in acetonitrile/water (8:2) under mild reaction conditions to provide the corresponding vic-diols and β-amino alcohols in excellent yields with high regioselectivity. Graphical Abstract
Gespeichert in:
| Veröffentlicht in: | Catalysis letters 2009-09, Vol.131 (3-4), p.480-484 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 484 |
|---|---|
| container_issue | 3-4 |
| container_start_page | 480 |
| container_title | Catalysis letters |
| container_volume | 131 |
| creator | Venkat Narsaiah, A Reddy, B. V. S Premalatha, K Reddy, S. S Yadav, J. S |
| description | Various epoxides and aziridines undergo smooth ring-opening with water in presence of 10 mol% of bismuth triflate in acetonitrile/water (8:2) under mild reaction conditions to provide the corresponding vic-diols and β-amino alcohols in excellent yields with high regioselectivity. Graphical Abstract |
| doi_str_mv | 10.1007/s10562-009-9927-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2258949729</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2258949729</sourcerecordid><originalsourceid>FETCH-LOGICAL-c370t-7e6fc628428d8a43acd6f8a14a9742b69d9face56632ba3dcf88c15e4a92dcf53</originalsourceid><addsrcrecordid>eNp9kM1OGzEUhUcVSOWnD9BVR6qQysLUvjMe292lUSiRkFjQSNlZxj_EaDJO7Qnt8Fg8CM9URxPBjtW91_d851qnKD4TfEEwZt8TwbQBhLFAQgBD4kNxRCgDxJlYHuQeE4IqBsuPxXFKDzgLGRFHxd-fPq23_erbfD4_R1PVq3Z4sqa8GkwM7ZB8KoMrZ5vwzxubStWZcvLkoze-s-lHnsuZc1572_Xl7dD1K7tHHr1Gxod2ZF6e0WTtu1BOWh1W-fW0OHSqTfbTvp4Ui8vZ7-kVur75NZ9OrpGuGO4Rs43TDfAauOGqrpQ2jeOK1EqwGu4aYYRT2tKmqeBOVUY7zjWhNu8hD7Q6Kb6OvpsY_mxt6uVD2MYun5QAlItaMBBZRUaVjiGlaJ3cRL9WcZAEy12-csxX5tjkLl-5Y872zipp1bqoOu3TKwiAMaW0zjoYdSmvunsb337wnvmXEXIqSHUfs_HiFjCpMGk44Riq_zg8lWQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2258949729</pqid></control><display><type>article</type><title>Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols</title><source>SpringerLink Journals - AutoHoldings</source><creator>Venkat Narsaiah, A ; Reddy, B. V. S ; Premalatha, K ; Reddy, S. S ; Yadav, J. S</creator><creatorcontrib>Venkat Narsaiah, A ; Reddy, B. V. S ; Premalatha, K ; Reddy, S. S ; Yadav, J. S</creatorcontrib><description>Various epoxides and aziridines undergo smooth ring-opening with water in presence of 10 mol% of bismuth triflate in acetonitrile/water (8:2) under mild reaction conditions to provide the corresponding vic-diols and β-amino alcohols in excellent yields with high regioselectivity. Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-009-9927-9</identifier><language>eng</language><publisher>Boston: Boston : Springer US</publisher><subject>Acetonitrile ; Alcohol ; Alcohols ; Bismuth ; Catalysis ; Chemistry ; Chemistry and Materials Science ; Diols ; Exact sciences and technology ; General and physical chemistry ; Industrial Chemistry/Chemical Engineering ; Organometallic Chemistry ; Physical Chemistry ; Regioselectivity ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Catalysis letters, 2009-09, Vol.131 (3-4), p.480-484</ispartof><rights>Springer Science+Business Media, LLC 2009</rights><rights>2009 INIST-CNRS</rights><rights>Catalysis Letters is a copyright of Springer, (2009). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-7e6fc628428d8a43acd6f8a14a9742b69d9face56632ba3dcf88c15e4a92dcf53</citedby><cites>FETCH-LOGICAL-c370t-7e6fc628428d8a43acd6f8a14a9742b69d9face56632ba3dcf88c15e4a92dcf53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-009-9927-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-009-9927-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22005554$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Venkat Narsaiah, A</creatorcontrib><creatorcontrib>Reddy, B. V. S</creatorcontrib><creatorcontrib>Premalatha, K</creatorcontrib><creatorcontrib>Reddy, S. S</creatorcontrib><creatorcontrib>Yadav, J. S</creatorcontrib><title>Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Various epoxides and aziridines undergo smooth ring-opening with water in presence of 10 mol% of bismuth triflate in acetonitrile/water (8:2) under mild reaction conditions to provide the corresponding vic-diols and β-amino alcohols in excellent yields with high regioselectivity. Graphical Abstract</description><subject>Acetonitrile</subject><subject>Alcohol</subject><subject>Alcohols</subject><subject>Bismuth</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diols</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Regioselectivity</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kM1OGzEUhUcVSOWnD9BVR6qQysLUvjMe292lUSiRkFjQSNlZxj_EaDJO7Qnt8Fg8CM9URxPBjtW91_d851qnKD4TfEEwZt8TwbQBhLFAQgBD4kNxRCgDxJlYHuQeE4IqBsuPxXFKDzgLGRFHxd-fPq23_erbfD4_R1PVq3Z4sqa8GkwM7ZB8KoMrZ5vwzxubStWZcvLkoze-s-lHnsuZc1572_Xl7dD1K7tHHr1Gxod2ZF6e0WTtu1BOWh1W-fW0OHSqTfbTvp4Ui8vZ7-kVur75NZ9OrpGuGO4Rs43TDfAauOGqrpQ2jeOK1EqwGu4aYYRT2tKmqeBOVUY7zjWhNu8hD7Q6Kb6OvpsY_mxt6uVD2MYun5QAlItaMBBZRUaVjiGlaJ3cRL9WcZAEy12-csxX5tjkLl-5Y872zipp1bqoOu3TKwiAMaW0zjoYdSmvunsb337wnvmXEXIqSHUfs_HiFjCpMGk44Riq_zg8lWQ</recordid><startdate>20090901</startdate><enddate>20090901</enddate><creator>Venkat Narsaiah, A</creator><creator>Reddy, B. V. S</creator><creator>Premalatha, K</creator><creator>Reddy, S. S</creator><creator>Yadav, J. S</creator><general>Boston : Springer US</general><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20090901</creationdate><title>Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols</title><author>Venkat Narsaiah, A ; Reddy, B. V. S ; Premalatha, K ; Reddy, S. S ; Yadav, J. S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-7e6fc628428d8a43acd6f8a14a9742b69d9face56632ba3dcf88c15e4a92dcf53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Acetonitrile</topic><topic>Alcohol</topic><topic>Alcohols</topic><topic>Bismuth</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diols</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Regioselectivity</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Venkat Narsaiah, A</creatorcontrib><creatorcontrib>Reddy, B. V. S</creatorcontrib><creatorcontrib>Premalatha, K</creatorcontrib><creatorcontrib>Reddy, S. S</creatorcontrib><creatorcontrib>Yadav, J. S</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Venkat Narsaiah, A</au><au>Reddy, B. V. S</au><au>Premalatha, K</au><au>Reddy, S. S</au><au>Yadav, J. S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2009-09-01</date><risdate>2009</risdate><volume>131</volume><issue>3-4</issue><spage>480</spage><epage>484</epage><pages>480-484</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Various epoxides and aziridines undergo smooth ring-opening with water in presence of 10 mol% of bismuth triflate in acetonitrile/water (8:2) under mild reaction conditions to provide the corresponding vic-diols and β-amino alcohols in excellent yields with high regioselectivity. Graphical Abstract</abstract><cop>Boston</cop><pub>Boston : Springer US</pub><doi>10.1007/s10562-009-9927-9</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2009-09, Vol.131 (3-4), p.480-484 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2258949729 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Acetonitrile Alcohol Alcohols Bismuth Catalysis Chemistry Chemistry and Materials Science Diols Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering Organometallic Chemistry Physical Chemistry Regioselectivity Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T06%3A39%3A54IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bismuth(III)-Catalyzed%20Hydrolysis%20of%20Epoxides%20and%20Aziridines:%20an%20Efficient%20Synthesis%20of%20vic-diols%20and%20%CE%B2-Amino%20Alcohols&rft.jtitle=Catalysis%20letters&rft.au=Venkat%20Narsaiah,%20A&rft.date=2009-09-01&rft.volume=131&rft.issue=3-4&rft.spage=480&rft.epage=484&rft.pages=480-484&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-009-9927-9&rft_dat=%3Cproquest_cross%3E2258949729%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2258949729&rft_id=info:pmid/&rfr_iscdi=true |