Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols

Bismuth(III)-Catalyzed Hydrolysis of Epoxides and Aziridines: an Efficient Synthesis of vic-diols and β-Amino Alcohols

Various epoxides and aziridines undergo smooth ring-opening with water in presence of 10 mol% of bismuth triflate in acetonitrile/water (8:2) under mild reaction conditions to provide the corresponding vic-diols and β-amino alcohols in excellent yields with high regioselectivity. Graphical Abstract

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Veröffentlicht in:Catalysis letters 2009-09, Vol.131 (3-4), p.480-484
Hauptverfasser: Venkat Narsaiah, A, Reddy, B. V. S, Premalatha, K, Reddy, S. S, Yadav, J. S
Format: Artikel
Sprache:eng
Schlagworte:
Acetonitrile
Alcohol
Alcohols
Bismuth
Catalysis
Chemistry
Chemistry and Materials Science
Diols
Exact sciences and technology
General and physical chemistry
Industrial Chemistry/Chemical Engineering
Organometallic Chemistry
Physical Chemistry
Regioselectivity
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Zusammenfassung:Various epoxides and aziridines undergo smooth ring-opening with water in presence of 10 mol% of bismuth triflate in acetonitrile/water (8:2) under mild reaction conditions to provide the corresponding vic-diols and β-amino alcohols in excellent yields with high regioselectivity. Graphical Abstract
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-009-9927-9