Mono and Bifunctional Catalysts for Styrene Oxide Isomerization or Hydrogenation

Mono and Bifunctional Catalysts for Styrene Oxide Isomerization or Hydrogenation

Styrene oxide can be effectively isomerized to phenyl-acetaldehyde (98%) over amorphous silica alumina catalysts under very mild liquid phase conditions. On the other hand, a copper catalyst prepared using a silica zirconia support gave up to 80% yield in the hydrogenation of styrene oxide to 2-phen...

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Veröffentlicht in:Catalysis letters 2011-04, Vol.141 (4), p.587-591
Hauptverfasser: Zaccheria, Federica, Psaro, Rinaldo, Ravasio, Nicoletta, Sordelli, Laura, Santoro, Federica
Format: Artikel
Sprache:eng
Schlagworte:
Aluminum oxide
Catalysis
Catalysts
Chemistry
Chemistry and Materials Science
Ethanol
Exact sciences and technology
General and physical chemistry
Hydrogenation
Industrial Chemistry/Chemical Engineering
Isomerization
Liquid phases
Organometallic Chemistry
Phenylacetaldehyde
Physical Chemistry
Silicon dioxide
Styrenes
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Zirconium dioxide
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Zusammenfassung:Styrene oxide can be effectively isomerized to phenyl-acetaldehyde (98%) over amorphous silica alumina catalysts under very mild liquid phase conditions. On the other hand, a copper catalyst prepared using a silica zirconia support gave up to 80% yield in the hydrogenation of styrene oxide to 2-phenyl-ethanol. Graphical Abstract
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-010-0543-5