Tailoring Sn-SBA-15 properties for catalytic isomerization of glucose

Tailoring Sn-SBA-15 properties for catalytic isomerization of glucose

[Display omitted] •The synthesis pH and Sn loading affect the structural, textural, and catalytic properties of SBA-15.•Catalysts with broad size distribution presented low TOF for fructose formation.•Sample containing extra framework SnO2 reached the lowest TOF for fructose.•TOF for fructose format...

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Veröffentlicht in:Applied catalysis. A, General General, 2019-07, Vol.581, p.37-42
Hauptverfasser: Lorenti, Juliana P., Scolari, Eduardo, Albuquerque, Elise M., Fraga, Marco A., Gallo, Jean Marcel R.
Format: Artikel
Sprache:eng
Schlagworte:
Biomass conversion
Catalysis
Catalysts
Catalytic activity
Fructose
Glucose
Glucose isomerization
Isomerization
Lewis acid catalyst
Microporosity
Parameters
Porosity
Size distribution
Sn-SBA-15
Unit cell
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Beschreibung
Zusammenfassung:[Display omitted] •The synthesis pH and Sn loading affect the structural, textural, and catalytic properties of SBA-15.•Catalysts with broad size distribution presented low TOF for fructose formation.•Sample containing extra framework SnO2 reached the lowest TOF for fructose.•TOF for fructose formation is affected by the solvent and increased as methanol 
ISSN:0926-860X
1873-3875
DOI:10.1016/j.apcata.2019.05.009