Nitric Oxide in Biological Denitrification:  Fe/Cu Metalloenzyme and Metal Complex NOx Redox Chemistry

Nitric Oxide in Biological Denitrification:  Fe/Cu Metalloenzyme and Metal Complex NOx Redox Chemistry

Wasser et al present an examination of metalloenzyme reactivity with nitric oxide, specifically metalloenzymes that both produce nitric oxide from nitrite and those that reduce nitric oxide to nitrous oxide. They also present a review of the inorganic coordination complex reactivity with nitric oxid...

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Veröffentlicht in:Chemical reviews 2002-04, Vol.102 (4), p.1201-1234
Hauptverfasser: WASSER, Ian M., DE VRIES, Simon, MOëNNE-LOCCOZ, Pierre, SCHRöDER, Imke, KARLIN, Kenneth D.
Format: Artikel
Sprache:eng
Schlagworte:
Biochemistry
Enzymes
Metals
Nitrogen
Oxygen
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Zusammenfassung:Wasser et al present an examination of metalloenzyme reactivity with nitric oxide, specifically metalloenzymes that both produce nitric oxide from nitrite and those that reduce nitric oxide to nitrous oxide. They also present a review of the inorganic coordination complex reactivity with nitric oxide, including Cu-NOx and Fe-NOx redox chemistries, since these metals are cofactors for the NO-producing and NO-consuming enzymes.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr0006627