Separation of strontium and yttrium in nitric acid solutions using zirconium titanium phosphate and Dowex exchangers

In this study, the sorption behavior of yttrium and strontium onto Dowex-S/S and synthesized zirconium titanium phosphate as cation exchanger from nitric acid medium was investigated using batch technique. The synthetic exchanger has been characterized by different analytical tools. Distribution beh...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2019-07, Vol.321 (1), p.39-47
Hauptverfasser: Ahmed, I. M., Hamed, Mostafa M., Aglan, R. F., Aly, M. I.
Format: Artikel
Sprache:eng
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Zusammenfassung:In this study, the sorption behavior of yttrium and strontium onto Dowex-S/S and synthesized zirconium titanium phosphate as cation exchanger from nitric acid medium was investigated using batch technique. The synthetic exchanger has been characterized by different analytical tools. Distribution behavior of Sr(II) and Y(III) as a function of HNO 3 concentration in the range 0.001–3.0 M has been studied. The maximum separation value was ( α Sr Y  = 18.78) at 0.001 M HNO 3 and 298 K while increasing temperature decreases the separation value. The sorption kinetics data followed the pseudo-second order model and thermodynamic data indicated an endothermic and spontaneous process.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-019-06583-w