Chemoselective Hydrogenation of Unsaturated Nitro Compounds to Unsaturated Amines by Ni-Sn Alloy Catalysts
Ni-Sn alloy catalysts were prepared and applied to the hydrogenation of 4-nitrostyrene at 383–423 K using H2 gas as the hydrogen donor. Ni3Sn2 alloy showed a significantly high conversion and selectivity towards 4-aminostyrene (Conv. 100%, Sel. 99%). Various unsaturated nitro compounds were also suc...
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| Veröffentlicht in: | Chemistry letters 2018-08, Vol.47 (8), p.971-974 |
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| container_title | Chemistry letters |
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| creator | Yamanaka, Nobutaka Hara, Takayoshi Ichikuni, Nobuyuki Shimazu, Shogo |
| description | Ni-Sn alloy catalysts were prepared and applied to the hydrogenation of 4-nitrostyrene at 383–423 K using H2 gas as the hydrogen donor. Ni3Sn2 alloy showed a significantly high conversion and selectivity towards 4-aminostyrene (Conv. 100%, Sel. 99%). Various unsaturated nitro compounds were also successfully converted into their corresponding unsaturated amines. |
| doi_str_mv | 10.1246/cl.180458 |
| format | Article |
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Ni3Sn2 alloy showed a significantly high conversion and selectivity towards 4-aminostyrene (Conv. 100%, Sel. 99%). 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Ni3Sn2 alloy showed a significantly high conversion and selectivity towards 4-aminostyrene (Conv. 100%, Sel. 99%). Various unsaturated nitro compounds were also successfully converted into their corresponding unsaturated amines.</description><subject>Amines</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Hydrogen storage</subject><subject>Hydrogenation</subject><subject>Nitro compounds</subject><subject>Selectivity</subject><subject>Tin base alloys</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNplkM1KxDAURoMoOI4ufIOAKxcd89smy6HojDDoQmddYppqS5vUJBX69kZmQMTF5S7u-b4LB4BrjFaYsPxO9yssEOPiBCwwZSJDBeanYIFonmcFIuQcXITQIYSEpGQBuvLDDC6Y3ujYfhm4nWvv3o1VsXUWugbubVBx8iqaGj610TtYumF0k60DjO7PeT201gT4Nicwe7Fw3fduhqWKqp9DDJfgrFF9MFfHvQT7h_vXcpvtnjeP5XqXaYZZzAg3FOWk4FgzWhOFRK2kkZQjI4iUmgiEFC9YGq65kpgUUhAlCp3XnMuGLsHNoXf07nMyIVadm7xNLytCGE4iKCGJuj1Q2rsQvGmq0beD8nOFUfWjstJ9dVCZ2PzIJlmtTk1OtybOnRqV_W3_H_wGnF540A</recordid><startdate>20180805</startdate><enddate>20180805</enddate><creator>Yamanaka, Nobutaka</creator><creator>Hara, Takayoshi</creator><creator>Ichikuni, Nobuyuki</creator><creator>Shimazu, Shogo</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20180805</creationdate><title>Chemoselective Hydrogenation of Unsaturated Nitro Compounds to Unsaturated Amines by Ni-Sn Alloy Catalysts</title><author>Yamanaka, Nobutaka ; Hara, Takayoshi ; Ichikuni, Nobuyuki ; Shimazu, Shogo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c414t-25e3062751c43d2a08da9e9350e8299c2800a574a575c5a9127982a87c6d559f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Amines</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Hydrogen storage</topic><topic>Hydrogenation</topic><topic>Nitro compounds</topic><topic>Selectivity</topic><topic>Tin base alloys</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yamanaka, Nobutaka</creatorcontrib><creatorcontrib>Hara, Takayoshi</creatorcontrib><creatorcontrib>Ichikuni, Nobuyuki</creatorcontrib><creatorcontrib>Shimazu, Shogo</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yamanaka, Nobutaka</au><au>Hara, Takayoshi</au><au>Ichikuni, Nobuyuki</au><au>Shimazu, Shogo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chemoselective Hydrogenation of Unsaturated Nitro Compounds to Unsaturated Amines by Ni-Sn Alloy Catalysts</atitle><jtitle>Chemistry letters</jtitle><date>2018-08-05</date><risdate>2018</risdate><volume>47</volume><issue>8</issue><spage>971</spage><epage>974</epage><pages>971-974</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Ni-Sn alloy catalysts were prepared and applied to the hydrogenation of 4-nitrostyrene at 383–423 K using H2 gas as the hydrogen donor. 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| fulltext | fulltext |
| identifier | ISSN: 0366-7022 |
| ispartof | Chemistry letters, 2018-08, Vol.47 (8), p.971-974 |
| issn | 0366-7022 1348-0715 |
| language | eng |
| recordid | cdi_proquest_journals_2241366322 |
| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Amines Catalysis Catalysts Hydrogen storage Hydrogenation Nitro compounds Selectivity Tin base alloys |
| title | Chemoselective Hydrogenation of Unsaturated Nitro Compounds to Unsaturated Amines by Ni-Sn Alloy Catalysts |
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