Cyclic Triad of Chlorophyll-a Derivative and Its Folded Conformer
A covalently linked triad of zinc pyropheophorbide-a, a derivative of naturally occurring chlorophyll-a as a photosynthetically active pigment, was prepared by full amidation of 1,4,7-triazacyclononane. The synthetic cyclic trimer produced a folded conformer with triple coordination of the amide car...
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Veröffentlicht in: | Chemistry letters 2018-03, Vol.47 (3), p.326-328 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng ; jpn |
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Zusammenfassung: | A covalently linked triad of zinc pyropheophorbide-a, a derivative of naturally occurring chlorophyll-a as a photosynthetically active pigment, was prepared by full amidation of 1,4,7-triazacyclononane. The synthetic cyclic trimer produced a folded conformer with triple coordination of the amide carbonyl groups to the central zinc atoms from the β-side in a solution, showing large circular dichroism couplets at the Qy and Soret regions that were based on intramolecular exciton coupling of the zinc chlorin components. |
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ISSN: | 0366-7022 1348-0715 |
DOI: | 10.1246/cl.171106 |