Synthesis of Coordinatively Unsaturated Iridium Complexes Having Functional 8-Quinolinolato Ligands: New Catalysts for Dehydrogenative Oxidation of Alcohols in Aqueous Media

New iridium complexes having functional 8-quinolinolato ligands have been synthesized. By single-crystal X-ray analysis, it was revealed that these new complexes had coordinatively unsaturated structure (five-coordinate trivalent iridium: 16e− complex). Furthermore, one of the new complexes exhibite...

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Veröffentlicht in:	Chemistry letters 2017-06, Vol.46 (6), p.808-810
Hauptverfasser:	Toyomura, Kazuki, Fujita, Ken-ichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols Aliphatic compounds Aqueous solutions Catalysis Catalytic activity Coordination compounds Dehydrogenation Iridium compounds Ketones Ligands Oxidation Single crystals X ray analysis
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Zusammenfassung:	New iridium complexes having functional 8-quinolinolato ligands have been synthesized. By single-crystal X-ray analysis, it was revealed that these new complexes had coordinatively unsaturated structure (five-coordinate trivalent iridium: 16e− complex). Furthermore, one of the new complexes exhibited high catalytic activity for the dehydrogenative oxidation of various aromatic and aliphatic secondary alcohols in aqueous media to give the corresponding ketones in good to excellent yields.
ISSN:	0366-7022 1348-0715
DOI:	10.1246/cl.170166